Hostname: page-component-586b7cd67f-l7hp2 Total loading time: 0 Render date: 2024-11-25T18:28:19.920Z Has data issue: false hasContentIssue false

Alloy Phase Stability Requirements in Single Crystal Superalloys

Published online by Cambridge University Press:  28 February 2011

David N. Duhl*
Affiliation:
Pratt and Whitney, Mail Stop 114-41 400 Main Street, East Hartford, CT 06108
Get access

Abstract

Alloy phase stability is a critical parameter in the design and implementation of nickel-base superalloys. To achieve the high temperature properties required of single crystal superalloys for application in gas turbine machinery, these alloys must have a stable gamma plus gamma prime microstructure for long periods of time at elevated temperatures. Significant deviation from this stable two phase microstructure, due to the precipitation of other phases, results in the loss of critical alloy properties which can have a deleterious impact on engine performance.

Empirical methods based on the electron vacancy concept, commonly employed to predict and prevent the formation of undesirable topologically close packed (TCP) phases such as sigma or mu in polycrystalline nickelbase superalloys, are also used with single crystal superalloys. These undesirable phases result in the loss of alloy properties primarily as a result of the depletion of refractory strengthening elements from the superalloy matrix. The consequence of the formation of undesirable TCP phases on alloy properties and subsequent single crystal component behavior is reviewed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Sims, C.T., J. Met. 18, 1119 (1966).Google Scholar
2. Das, D.K., Rideout, S.P. and Beck, P.A., TMS-AIME 194, 1071 (1952).Google Scholar
3. Greenfield, P., and Beck, P.A., TMS-AIME 200, 253 (1954).Google Scholar
4. Greenfield, P., and Beck, P.A., TMS-AIME 206, 265 (1956).Google Scholar
5. Sully, A.H. and Heal, T.J., Research 1, 228 (1948).Google Scholar
6. Pauling, L., Phys. Rev. 54, 899 (1938).Google Scholar
7. Boesch, W.J. and Slaney, J.S., Met. Prog. 86 (1), 109 (1964).Google Scholar
8. Woodyatt, L.R., Sims, C.T. and Beattie, H.J. Jr., TMS-AIME 236, 519 (1966).Google Scholar
9. Morinaga, M., Yukawa, N., Adachi, H., and Ezaki, H., in Superalloys 1984 - Proceedings of the Fifth International Symposium on Superalloys, edited by Gell, M. et al. , (The Metallurgical Society, Warrendale, PA 1984) pp 523532.Google Scholar