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Advanced Metal/Ceramic Catalysts for Hydrogen Generation by Steam Reforming of Hydrocarbons

Published online by Cambridge University Press:  10 February 2011

S. F. Tikhov
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
V. A. Sadykov
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
A. N. Salanov
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
Yu. A. Potapov
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
G. S. Litvak
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
S. V. Tsybulya
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
S. N. Pavlova
Affiliation:
Boreskov Institute of catalysis of the SB RAN, Pr. Lavrentyeva, 5, Novosibirsk, 630090, RUSSIA.
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Abstract

The main features of porous metal/ceramic catalysts for hydrocarbons steam reforming their formation via hydrothermal treatment of the powdered aluminum and lanthanum nickelate mixture in the confined space are elucidated. For catalysts obtained via this route, their polymodal pore structure was found to approach the optimum level. The phase composition of the active component precursor was shown to have a great impact on the specific catalytic activity of catalysts.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1. Rostrup-Nielsen, J.P. in Catalysis: Sci.(g)Tech., edited by Anderson, J.R. and Boudart, M. (Akademie-Verlag-Berlin 5, 1984), p. 1118.Google Scholar
2. Isupova, L.A., Sadykov, V.A., Tikhov, S.F., Kimkhai, O.N., Kovalenko, O.N., Kustova, G.N., Ovsyannikova, I.A., Dovbii, Z.A., Kryukova, G.N., Rozovskii, A. Ya., Tretyakov, V.F., Lunin, V.V., Catal. Today, 27, p. 249 (1996).Google Scholar
3. Tikhov, S.F., Salanov, A.N., Palesskaya, Yu.A., Sadykov, V.A., Kustova, G.N., Litvak, G.S., Rudina, N.A., Zaikovskii, V.A., Tsybulya, S.V., React. Kinet. Catal. Lett. (1998) [accepted].Google Scholar
4. Parkhomenko, V.D., Tsybulev, P.N., Krasnokutskii, Yu.I., Plasmochemical Technology. Vischa Shkola, Kiev, 1991, pp. 99102 (in Russian).Google Scholar
5. Alem, T., “Particle Size Measurement”, Capt. Hill, London, 1981, p. 590.Google Scholar
6. Fenelonov, V.B. React. Kinet. Catal. Lett., 52, 367 (1994).Google Scholar
7. Klevtsov, P.V., Sheina, L.P., Izv. AN SSSR. Neorg. Materiali, 1, p. 912 (1965) [in Russian].Google Scholar
8. Chalii, V.P., Metal hydroxydes. Naukova Dumka, Kiev, 1972, p. 94 [in Russian].Google Scholar
9. Popilskii, R. Ya., Kondratov, F.D., Pressing of the ceramic materials. Metallurgiya, Moscow, 1968, p. 63 [in Russian].Google Scholar
10. McGeary, R.K., J. Amer. Ceram. Soc., 44, p. 513 (1961).Google Scholar
11. Fenelonov, V.B., Tarasova, D.V., Gavrilov, V. Yu., Kinetika I kataliz, 19, p. 222 (1978) [in Russian].Google Scholar
12. Bobrov, N.N., Bobrova, I.I., Sobyanin, V.A., Kinetika I kataliz, 34, p. 686 (1993) [in Russian].Google Scholar