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X-Ray Spectroscopic Study of the PdxC60Chemical Bonding

Published online by Cambridge University Press:  15 February 2011

A.V. Okotrub ,
E.S. Fomin ,
V.N. Ivanova  and
L.N. Mazalov
A.V. Okotrub
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
E.S. Fomin
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
V.N. Ivanova
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
L.N. Mazalov
Affiliation:
Institute of Inorganic Chemistry SB RAS, pr. Lavrent'eva 3, Novosibirsk 630090, Russia
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Abstract

The CKα -emission spectra of the PdxC60 compounds were obtained. To interpret the spectrum and study the Pd - C60 chemical bond structure, the SCF Xα-SW calculations of the clusters simulating the bonding between two fullerene molecules and a Pd bridge atom were carried out. On the base of the obtained data, a diagram of the electron interaction between the Pd atoms and fullerenes was constructed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 437: Symposium DD – Applications of Synchrotron Radiation to III , 1996 , 155
Copyright
Copyright © Materials Research Society 1996

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References

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