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XPS Study of Alkali Graphite Intercalation Compounds

Published online by Cambridge University Press:  15 February 2011

G. K. Wertheim  and
S. B. Dicenzo
G. K. Wertheim
Affiliation:
Bell Laboratories, 600 Mountain Avenue, Murray Hill, New Jersey 07974, USA
S. B. Dicenzo
Affiliation:
Bell Laboratories, 600 Mountain Avenue, Murray Hill, New Jersey 07974, USA
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Abstract

Carbon 1s X-ray photoemission spectra of alkali graphite intercalation compounds are shown to provide detailed information about the distribution of charge among the carbon layers and atoms. The interior layers of higher stage compounds contain little charge and remain similar to graphite. The charge in the bounding layers is strongly localized to screen the alkali intercalate ions. The c-axis charge distribution in KC12n is in reasonable accord with the electrostatic screening model of Safran and Hamann.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 20: Symposium H – Intercalated Graphite , 1982 , 71
Copyright
Copyright © Materials Research Society 1983

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References

REFERENCES

1. van Attekum, P. M. Th. M., Wertheim, G. K., Phys. Rev. Lett. 43, 1896 (1979).CrossRefGoogle Scholar
2. Mele, E. J. and Ritsko, J. J., Phys. Rev. 43, 86 (1979).Google Scholar
3. Wertheim, G. K., van Attekum, P. M. Th. M. and Basu, S., Solid State Commun. 33, 1127 (1980).Google Scholar
4. Holzwarth, N., Rabii, S. and Girifalco, L. A., Phys. Rev. B. 18, 5190 (1978).CrossRefGoogle Scholar
5. DiCenzo, S. B., Basu, S. and Wertheim, G. K., Synthetic Metals 3, 139 (1981)CrossRefGoogle Scholar
6. DiCenzo, S. B., Basu, S., Wertheim, G. K., Buchanan, D. N. E. and Fischer, J. E., Phys. Rev. B 25, 620 (1982).Google Scholar
7. Low temperature data have recently been obtained and preliminary analysis yields results quite similar to those described here. (M. Preil, private communication.)Google Scholar
8. DiCenzo, S. B., Wertheim, G. K., Basu, S. and Fischer, J. E., Phys. Rev. B 24, 2270 (1981).CrossRefGoogle Scholar
9. Bach, B., C. R. Acad. Sci. 273, 666 (1971).Google Scholar
10. Safran, S. A. and Hamann, D. R., Phys. Rev. B 23, 565 (1981).CrossRefGoogle Scholar
11. Berker, A. N., Kambe, N., Dresselhaus, G. and Dresselhaus, M. S., Phys. Rev. Lett. 45, 1452 (1980).Google Scholar
12. Caswell, N., Solin, S. A., Hayes, T. M. and Hunter, S. J., Physica (Utrecht) 99B, 463 (1980).Google Scholar
13. Doniach, S. and Sunjic, M., J. Phys. C 3, 285 (1970).CrossRefGoogle Scholar
14. DiCenzo, S.S., Phys. Rev. B26, 5878 (1982).CrossRefGoogle Scholar