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Water-soluble Poly(4-styrenesulfonic acid-co-maleic acid)-stabilized Nickel(0) and Cobalt(0) Nanoclusters as Highly Active Catalysts in Hydrogen Generation from the Hydrolysis of Ammonia-Borane

Published online by Cambridge University Press:  31 January 2011

Önder Metin  and
Saim Özkar
Önder Metin
Affiliation:
[email protected], Middle East Technical University, Chemistry, Ankara, Turkey
Saim Özkar
Affiliation:
[email protected], Middle East Technical University, Chemistry, Ankara, Turkey
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Abstract

Water soluble poly(4-styrenesulfonic acid-co-maleic acid), PSSA-co-MA, stabilized nickel(0) and cobalt(0) nanoclusters were prepared for the first time from the reduction of nickel(II) chloride and cobalt(II) chloride by using minimum amount of sodium borohydride shortly before their usage as catalysts in the hydrolysis of ammonia-borane (AB) in the same medium at room temperature. PSSA-co-MA stabilized nickel(0) and cobalt(0) nanoclusters showed high catalytic activity in hydrogen generation from the hydrolysis of AB even at low temperature.

Keywords

catalytickineticsenergy storage
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1217: Symposium Y – Catalytic Materials for Energy, Green Processes and Nanotechnology , 2009 , 1217-Y08-14
Copyright
Copyright © Materials Research Society 2010

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References

1 Schlapbach, L. and Züttel, A., Nature, 414, 353 (2001).Google Scholar
2 Züttel, A., Mater. Today, 6, 24 (2003).Google Scholar
3 Marder, T. B., Angew. Chem., Int. Ed., 46, 8116 (2007).Google Scholar
4(a) Chandra, M., Xu, Q., J. Power Sources, 156, 190 (2006) (b) S.D. Kalidindi, M. Indirani, B.R. Jagirdar, Inorg. Chem., 47, 7424 (2008) (c) M. Chandra, Q. Xu, J. Power Sources 163, 364 (2006). (d) S.D. Kalidindi, U. Sayal, B.R. Jagirdar, Phys. Chem. Chem. Phys., 10, 5870 (2008) (e) S. Basu, A. Brockman, P. Gagore, Y. Zheng, P.V. Ramachandran, W.N. Delgass, J. Power Sources, 188, 238 (2009). (f) J-M. Yan, X-B. Zhang, S. Han, H. Shioyama, Q. Xu, Inorg. Chem. 48, 7389 (2009). (g) T.Umegaki, J-M. Yan, X-B. Zhang, H. Shioyama, N. Kuriyama, Q. Xu, Int. J. Hydrogen Energy, 34, 3816 (2009).Google Scholar
5(a) Cheng, F., Ma, H., Li, Y., J. Chen, Inorg. Chem., 46, 788 (2007) (b) T.J. Clark, G.R. Whittell, I. Manners, Inorg. Chem., 46, 7522 (2007). (c) M. Chandra, Q. Xu, J. Power Sources 168, 135 (2007).Google Scholar