Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-19T21:53:15.853Z Has data issue: false hasContentIssue false

VHF Large Area Plasma Processing on Moving Substrats

Published online by Cambridge University Press:  17 March 2011

J. Kuske
Affiliation:
Forschungs- und Applikationslabor Plasmatechnik GmbH Dresden, D-01217 Dresden, Gostritzer Straße 61-63, F.R. Germany
U. Stephan
Affiliation:
Forschungs- und Applikationslabor Plasmatechnik GmbH Dresden, D-01217 Dresden, Gostritzer Straße 61-63, F.R. Germany
R. Terasa
Affiliation:
Semiconductor and Microsystems Technology Laboratory, Dresden University of Technology, D-01062 Dresden, Mommsenstraße 13, F.R. Germany
H. Brechtel
Affiliation:
Semiconductor and Microsystems Technology Laboratory, Dresden University of Technology, D-01062 Dresden, Mommsenstraße 13, F.R. Germany
A. Kottwitz
Affiliation:
Semiconductor and Microsystems Technology Laboratory, Dresden University of Technology, D-01062 Dresden, Mommsenstraße 13, F.R. Germany
Get access

Abstract

The production of amorphous and microcrystalline silicon, e.g. for solar cells, requires large area, high-deposition rate plasma reactors. Increasing the frequency from the conventional 13.56MHz up to VHF has demonstrated higher deposition and etch rates and lower particle generation, a reduced ion bombardement and lower breakdown, process and bias voltages. But the use of VHF for large area systems leads to some problems. The non-uniformity of deposition rate increases due to the generation of standing waves and evanescent waveguide modes at the electrode surface. One possibility to process large area substrates is the use of a one-dimensional extended, homogeneous plasma source in combination with a moving substrate. The requirements, which result from the deposition process and from the RF-engineering, corresponds with the developed plasma source, using deposition frequencies in the VHF-range (50-100 MHz), almost perfectly.

Using a source of 550mm length experiments were done with 81.36MHz at RF power densities of 70-180mW/cm2, silane/ hydrogen pressures of 5-30Pa and flow rates of 10-300sccm. The measured potential distribution error was ±2%. Optical emission spectroscopy delivered discharge intensity errors of ±3-10%. Deposition rates up to 20µm/h for amorphous silicon (60Å/s) and film thickness inhomogenities less than ±5% were achieved (with an area of the moved substrate of 30cm–30cm). Experimental results of the film properties will be discussed in relation to the deposition parameters and compared with complementary experiments, carried out on a small scale equipment with excitation frequencies up to 165 MHz.

Type
Research Article
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCE

[1] Stephan, U., Kuske, J., Grüger, H., Kottwitz, A., MRS Symp. Proc. 557, 157162 (1999)Google Scholar
[2] German patent application DE-OS 421 2231Google Scholar
[3] Grüger, H., Terasa, R., Haiduk, A., Kottwitz, A., MRS Symp. Proc. 557, 609 (1999)Google Scholar
[4] Kuske, J., Stephan, U., Nowak, W., Röhlecke, S., Kottwitz, A., MRS Symp. Proc. 467, 591595 (1997)Google Scholar
[5] Sansonnens, L. et al. , Proc. of 13th EC PSEC, 319 (1995)Google Scholar
[6] Bubenzer, A., Schmitt, J. P. M., Vacuum 41, 19571961 (1990)Google Scholar
[7] Hautala, J. et al. , MRS Symp. Proc. 420, 8392 (1996)Google Scholar
[8] Hapke, P., Thesis, RWTH Aachen, Germany, (1995)Google Scholar
[9] Torres, P., Keppner, H., Meier, J., Kroll, U., Beck, N., Shah, A., Phys. Stat. Sol. A 163, R9 (1997)10.1002/1521-396X(199710)163:2<R9::AID-PSSA99999>3.0.CO;2-73.0.CO;2-7>Google Scholar
[10] Hapke, P., Finger, F., J. Non-Cryst. Solids 227–230, 862 (1998)Google Scholar