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Vanadium Oxide Nanotubes: New Synthesis Route and Mechanism of Formation.

Published online by Cambridge University Press:  01 February 2011

Maguy Jaber ,
Nathalie Steunou ,
Thierry Azaïs  and
Jacques Livage
Maguy Jaber
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. [email protected]
Nathalie Steunou
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. [email protected]
Thierry Azaïs
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. [email protected]
Jacques Livage
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574), Université P. et M. Curie, T54-E5, 4 place jussieu, 75252 Paris cedex 05, France. [email protected]
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Abstract

The synthesis of vanadium oxide nanotubes containing phosphorus (VPOx-NT) is described. A mixture of V2O5.nH2O gels, phosphoric acid and hexadecylamine was heated under hydrothermal conditions at 180°C for 7 days. The VPOx nanotubes were characterized by X-ray diffraction, scanning and transmission electron microscopy, 51V and 31P solid state NMR. In-situ experiments were performed in order to get a better understanding of the mechanism of these nanotubes formation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 847: Symposium EE – Organic/Inorganic Hybrid Materials , 2004 , EE9.24
Copyright
Copyright © Materials Research Society 2005

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References

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