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Vanadium Oxide Frameworks Modified with Transition Metals

Published online by Cambridge University Press:  18 March 2011

Peter Y. Zavalij  and
M. Stanley Whittingham
Peter Y. Zavalij
Affiliation:
Institute for Materials Research and Chemistry Department, State University of New York at Binghamton, Binghamton, NY, 13902-6016, USA
M. Stanley Whittingham
Affiliation:
Institute for Materials Research and Chemistry Department, State University of New York at Binghamton, Binghamton, NY, 13902-6016, USA
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Abstract

It is well known that vanadium oxides readily form open structures that defines the potential use of vanadium compounds as cathode materials for lithium batteries. In order to stabilize open frameworks during electrochemical cycling and improve their performance, vanadium oxide can be modified with other transition metals. This work presents the structural analysis of vanadium oxide frameworks modified with Mn and Zn as well as reporting on several interesting new structures, such as TMA4[Zn4V21O58] and NaMn(VO3)4·2H2O.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG10.7
Copyright
Copyright © Materials Research Society 2001

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References

REFERENCES

1. Zavalij, P. Y. and Whittingham, M. S.. Acta Cryst., B55, 627–663 (1999).Google Scholar
2. Chirayil, T., Zavalij, P. Y. and Whittingham, M. S.. Chem. Mater., 10, 2629–2640 (1998).Google Scholar
3. Chirayil, T. G., Boylan, E. A., Mamak, M., Zavalij, P. Y., and Whittingham, M. S.. Chem. Commun., 33–34 (1997).Google Scholar
4. Zhang, F., Zavalij, P. Y., and Whittingham, M. S.. J. Mater. Chem., 9, 3137–3140 (1999).Google Scholar
5. Zhang, F., Zavalij, P. Y., and Whittingham, M. S.. J. Phys. Chem. Solids., (2000) (in press).Google Scholar
6. Zavalij, P. Y., Zhang, F., and Whittingham, M. S.. Acta Cryst., C53, 1738–1739 (1997).Google Scholar
7. Zhang, F., Zavalij, P., and Whittingham, M. S.. Electrochem. Commun., 564–567 (1999).Google Scholar
8. Legagneur, V., Liao, J.-H., An, Y., Salle, A. Le Gal La, Verbaere, A., Piffard, Y., and Guyomard, D.. Solid State Ionics, 133, 161–170 (2000)Google Scholar
9. Andreetti, G. D., Calestani, G., Montenero, A., and Bettinelli, M.. Z. Kristallogr., 168, 53–58 (1984).Google Scholar
10. Kozlowski, R. and Stadnicka, K.. J. Solid State Chem., 39, 271–276 (1981).Google Scholar
11. Ngala, K., Zavalij, P., and Whittingham, M.S.. Mater. Res. Soc. Proc., (2001) (in press).Google Scholar
12. Zhang, F., Zavalij, P. Y., and Whittingham, M. S.. Mater. Res. Soc. Proc., 496, 367–372 (1998).Google Scholar
13. Oka, Y., Tamada, O., Yao, T., and Yamamoto, N.. J. Solid State Chem., 126, 65–73 (1996).Google Scholar
14. Lloyd, D. J. and Galy, J.. Cryst. Struct. Commun., 2, 209–211 (1973).Google Scholar
15. Mueller-Buschbaum, H. and Kobel, M.. Z. Anorg. Allg. Chem., 596, 23–28 (1991).Google Scholar
16. Muller, J., Joubert, J. C., and Marezio, M.. J. Solid State Chem., 27, 367–382 (1979).Google Scholar
17. Saux, M. and Galy, J.. Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, Serie C, 276, 81–84 (1973).Google Scholar
18. Oka, Y., Yao, T., Yamamoto, N., and Ueda, Y.. J. Solid State Chem., 141, 133–139 (1998).Google Scholar
19. Wang, X., Liu, L., Bontchev, R., and Jacobson, A. J.. Chem. Commun., 1989, 1009–1010 (1998).Google Scholar