Hostname: page-component-cd9895bd7-fscjk Total loading time: 0 Render date: 2024-12-27T02:18:47.072Z Has data issue: false hasContentIssue false
  • English
  • Français

Vacuum Ultraviolet Irradiation of Polymers

Published online by Cambridge University Press:  10 February 2011

A. C. Fozza ,
A. Bergeron ,
J. E. Klemberg-Sapieha  and
M. R. Wertheimer
A. C. Fozza
Affiliation:
Groupe des Couches Minces and Department of Engineering Physics and Materials Engineering, École Polytechnique, Montréal, Qc H3C 3A7, CANADA
A. Bergeron
Affiliation:
Groupe des Couches Minces and Department of Engineering Physics and Materials Engineering, École Polytechnique, Montréal, Qc H3C 3A7, CANADA
J. E. Klemberg-Sapieha
Affiliation:
Groupe des Couches Minces and Department of Engineering Physics and Materials Engineering, École Polytechnique, Montréal, Qc H3C 3A7, CANADA
M. R. Wertheimer
Affiliation:
Groupe des Couches Minces and Department of Engineering Physics and Materials Engineering, École Polytechnique, Montréal, Qc H3C 3A7, CANADA
Get access

Abstract

The interest in incoherent sources for wavelength selective photochemistry has increased lately, but little is still known about the behavior of polymers when exposed to far UV and vacuum UV (VUV) radiation, for example that emitted from low-pressure plasmas. In order to study VUV-UV effects on several polymers (polyethylene - PE, polystyrene - PS, hexatriacontane - HTC, polymethylmethacrylate - PMMA and polycarbonate - PC), we used the wellcharacterized emissions from hydrogen and hydrogen/argon mixture plasmas as light sources. Mass changes were measured in-situ using a quartz crystal microbalance (QCM); irradiated samples were analyzed ex-situ by XPS, spectroscopic ellipsometry, and AFM.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 544: Symposium Y – Plasma Deposition and Treatment of Polymers , 1998 , 109
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Fozza, A.C., Kruse, A., Hollander, A., Ricard, A., and Wertheimer, M.R., J. Vac. Sci. Technol. A 16, 72 (1997).Google Scholar
[2] Fozza, A.C., Roch, J., Klemberg-Sapieha, J.E., Kruse, A., Hollander, A., and Wertheimer, M.R., Nucl. Instrum. Methods Phys. Res. B 131, 205 (1997).Google Scholar
[3] Wertheimer, M.R., Fozza, A.C., and Hollander, A., Nucl. Instrum. Methods Phys. Res. B (in press).Google Scholar
[4] Okabe, H., Photo-chemistry of small molecules (John Wiley & Sons, New York, 1978), pp. 139–183.Google Scholar
[5] HollAinder, A., Klemberg-Sapieha, J.E., and Wertheimer, M.R., J. Polym. Sci.: Polym. Chem. 33, 2073 (1995).Google Scholar
[6] Sobrinho, A.S. da Silva, Schihler, N., Klemberg-Sapieha, J.E., Wertheimer, M.R., Andrews, M. and Gujrathi, S.C., J. Vac. Sci. Technol. A 16, 2021 (1998).Google Scholar