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Unsaturated Zone Waters From the Nopal I Natural Analog, Chihuahua, Mexico - Implications for Radionuclide Mobility at Yucca Mountain

Published online by Cambridge University Press:  10 February 2011

David A. Pickett  and
William M. Murphy
David A. Pickett
Affiliation:
Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute, 6220 Culebra Rd., San Antonio, TX 78238, USA
William M. Murphy
Affiliation:
Center for Nuclear Waste Regulatory Analyses, Southwest Research Institute, 6220 Culebra Rd., San Antonio, TX 78238, USA
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Abstract

Chemical and U-Th isotopic data on unsaturated zone waters from the Nopal I natural analog reveal effects of water-rock interaction and help constrain models of radionuclide release and transport at the site and, by analogy, at the proposed nuclear waste repository at Yucca Mountain. Geochemical reaction-path modeling indicates that, under oxidizing conditions, dissolution of uraninite (spent fuel analog) by these waters will lead to eventual schoepite precipitation regardless of initial silica concentration provided that groundwater is not continuously replenished. Thus, less soluble uranyl silicates may not dominate the initial alteration assemblage and keep dissolved U concentrations low. Uranium-series activity ratios are consistent with models of U transport at the site and display varying degrees of leaching versus recoil mobilization. Thorium concentrations may reflect the importance of colloidal transport of low-solubility radionuclides in the unsaturated zone.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 556: Symposium QQ – Scientific Basis for Nuclear Waste Management XXII , 1999 , 809
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Murphy, W. and Pearcy, E. in Scientific Basis for Nuclear Waste Management XV, edited by Sombert, C.G. (Mater. Res. Soc. Proc. 257, Pittsburgh, PA 1992), pp. 521–527.Google Scholar
2. Pearcy, E., Prikryl, J., Murphy, W., and Leslie, B., Appl. Geochem. 9, 713 (1994).Google Scholar
3. Pearcy, E., Prikryl, J., and Leslie, B., Appl. Geochem. 10, 685 (1995).Google Scholar
4. Prikryl, J., Pickett, D., Murphy, W., and Pearcy, E., J. Contam. Hydrol. 26, 61 (1997).Google Scholar
5. Murphy, W., Pearcy, E., and Pickett, D. in Seventh EC Natural Analogue Working Group Meeting Proceedings, edited by Maravic, H. von and Smellie, J., (EUR 17851 EN, European Commission, Luxembourg 1997), pp. 105–112.Google Scholar
6. Pickett, D., Prikryl, J., Murphy, W., and Pearcy, E., submitted to Appl. Geochem. (1998).Google Scholar
7. Murphy, W. and Codell, R., this volume.Google Scholar
8. Moran, S., Hoff, J., and Edwards, R., Geophys. Res. Lett. 22, 2589 (1995).Google Scholar
9. Wolery, T., UCRL-MA- 110662 PT1, Lawrence Livermore National Laboratory, Livermore, CA, 1992.Google Scholar
10. Ogard, A. and Kerrisk, J., LA-10188-MS, Los Alamos National Laboratory, Los Alamos, NM, 1985.Google Scholar
11. Yang, I., Rattray, G., and Yu, P., Water-Resources Investigations Report 96-4058, U.S. Geological Survey, Denver, CO, 1996.Google Scholar
11. Clark, D., Hobart, D., and Neu, M., Chem. Rev. 95, 25 (1995).Google Scholar
13. Nguyen, S., Silva, R., Weed, H., and Andrews, J. Jr,. J. Chem. Thermo. 24, 359 (1992).Google Scholar
14. Moll, H., Geipel, G., Matz, W., Bernhard, G., and Nitsche, H., Radioch. Acta 74, 3 (1996).Google Scholar
15. Murphy, W. in Scientific Basis for Nuclear Waste Management XX, edited by Gray, W.J. and Triay, I.R. (Mater. Res. Soc. Proc. 465, Pittsburgh, PA 1997), pp. 713–720.Google Scholar