Hostname: page-component-cd9895bd7-jkksz Total loading time: 0 Render date: 2024-12-27T01:57:54.892Z Has data issue: false hasContentIssue false
  • English
  • Français

Unimolecular Precursors to Binary Metal Sulfides: Mechanistic and Structural Correlations

Published online by Cambridge University Press:  10 February 2011

Rodney D. Schluter ,
Gertrude Kräuter  and
William S. Rees Jr
Rodney D. Schluter
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
Gertrude Kräuter
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
William S. Rees Jr
Affiliation:
School of Chemistry and Biochemistry, School of Materials Science and Engineering, and the Molecular Design Institute, Georgia Institute of Technology, Atlanta, GA 30332-0400
Get access

Abstract

The roles which ligand size and stability play in influencing solid-state thermolyses products and phases are developed for a group of metal thiolate compounds. The exploration includes Pb(SR)2 [R = t-Bu, i-Bu, s-Bu], Cd(SR*)2 [ R* = i-Pr, I-Bu, Bz], ClHgSR** [ R** = i- Pr, neo-Pent, Bz] and In(SR***)3 [R*** = 2,4,6-(i-Pr)3C6H2, 2-CH3O-5-CH3C6H3, o- C6H4CH2N(CH3)2]. In several examples, the precursors have been characterized by single crystal X-ray diffraction. In most cases, solid-state decomposition products have been identified by XRPD, and volatile decomposition products have been identified by GC/MS. All precursors have been studied by TGA.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 410: Symposium S – Covalent Ceramics III-Science and Technology of Non-Oxides , 1995 , 85
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. a) Cowley, A. H. and Jones, R. A., Angew. Chem. Int. Ed. Engl. 28, 1208 (1989); b) A. H. Cowley and R. A. Jones, Polyhedron 13, 1149 (1994).Google Scholar
2. a) MacInnes, A. N., Power, M. B. and Barron, A. R., Chem. Mater. 4, 11 (1992); b) W. S. Rees, Jr., D. M. Green, T. J. Anderson, E. Bretschneider, B. Pathangey, C. Park, J. Kim, J. Electron. Mater. 21, 361 (1992); c) G. Kräuter and W. S. Rees, Jr., J. Mater. Chem. 5, 1265 (1995).Google Scholar
3. a) Kräuter, G., Favreau, P. and Rees, W. S. Jr., Chem. Mater. 6, 543 (1994); b) W. S. Rees, Jr. and G. Kräuter, Phosphorus, Sulfur, and Silicon 87, 219 (1994); c) G. Krauter, V. L. Goedken, B. Neumuller and W. S. Rees, Jr., Mat. Res. Soc. Symp. Proc. 327, 35 (1994); d) W. S. Rees, Jr. and G. Krauter, Mat. Res. Soc. Symp. Proc. 327, 3 (1994); e) G. Krauter, B. Neumuiller, V. L. Goedken, and W. S. Rees, Jr., Chem. Mater., in press (1996).Google Scholar
4. Steigerwald, M. L. and Sprinkle, C. R., J. Am. Chem. Soc. 109, 7200 (1987).Google Scholar
5. Kumar, R., Mabrouk, H. E., Tuck, D. G., J. Chem. Soc., Dalton Trans. 1045 (1988).Google Scholar
6. Bradley, D. C. and Marsh, C. H., Chem. Ind., 361 (1967).Google Scholar
7. Krauter, G. and Rees, W. S., Jr., submitted for publication.Google Scholar
8. Morrison, R. T. and Boyd, R. N., Organic Chemistry, 2nd ed., Allyn and Bacon, Boston, 1966.Google Scholar
9. Schluter, R. D., Luten, H. A. and Rees, W. S., Jr., Mat. Res. Soc. Symp. Proc. in press (1996).Google Scholar