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Tm Doping of Lead Telluride
Published online by Cambridge University Press: 21 February 2011
Abstract
Doping with the rare earth elements is widely used for the improvement of parameters of the PbTe-based lasers. It has been found that Tm is a donor in PbTe, and the solubility of TmTe in PbTe does not exceed 7 - 8 mol.%. Electron concentration in obtained PbTe(Tm) crystals reaches 4.1020 cm-3 and depends on Tm content and on deviation from stoichiometry. The analysis of the magnetoresistance oscillation picture shows no variation of the energy spectrum parameters for Tm contents less than I at.%. The g-factor does not change as well. This may be due to a rather small exchange interaction between Tm atom, which is magnetic in both +2 and +3 valence states, and band electrons. The experimental data for PbTe(Tm) are compared with the properties of semimagnetic PbTe(Cr) with quite the same electron consentration value.
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