Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-25T17:29:34.971Z Has data issue: false hasContentIssue false

Thermodynamics and Microstructure Development in the Thin Film Reaction of Aluminum on Silicon Carbide

Published online by Cambridge University Press:  15 February 2011

T. S. Hayes
Affiliation:
School of Materials Engineering, Purdue University, W. Lafayette, IN 47907
F. T. Ray
Affiliation:
School of Materials Engineering, Purdue University, W. Lafayette, IN 47907
K. P. Trumble
Affiliation:
School of Materials Engineering, Purdue University, W. Lafayette, IN 47907
E. P. Kvam
Affiliation:
School of Materials Engineering, Purdue University, W. Lafayette, IN 47907
Get access

Abstract

A refined thernodynamic analysis of the reaction between molen Al and SiC is presented. The calculations indicate much higher Si concentrations for saturation with respect to AkC 3 formation than previously reported. Preliminary microstructural studies confirm the formation of interfacial A14C3 for pure Al thin films on SiC reacted at 9000C. The implications of the calculations and experimental observations for the production of ohmic contacts to p-type SiC are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Davis, R.F., Kelner, G., Shur, M., Palmour, J.W., Edmond, J.A., Trans. IEEE 79, 677 (1991).Google Scholar
2. Viala, J.C., Fortier, P., Bouix, J., J. Mater. Sci. 25, 1842 (1990).Google Scholar
3. Lloyd, D. J., Lagace, H., McLeod, A., Morris, P. L., Mater. Sci. Eng. A 107, 73 (1989).Google Scholar
4. Iseki, T., Kameda, T., Maruyama, T., J. Mater. Sci. 19, 1692 (1984).Google Scholar
5. Isaikin, A. S., Chubarov, V. M., Trefilov, B. F., Silaev, V. A., Gorelov, Yu. A., Metallovedenie I Termicheskaya Obrabotka Metallov 11, 32 (1980).Google Scholar
6. Nakae, H., Yamaota, K., Sato, K., Mat. Trans, JIM 32,531 (1991).Google Scholar
7. Kubaschewski, O., Alcock, C. B., Metallurgical Thermochemistry, Pergamon (1985), p. 327.Google Scholar
8. Murray, J. L., McAlister, A. J., Bull. Alloy Phase Diagrams 5,7484 (1984).Google Scholar
9. Ferro, A. C., Derby, B., Acta Metall. Mater. 43, 3061 (1995).Google Scholar
10. Handwerker, C. A., Vaudin, M. D., Kattner, U. R., Lee, D. in Metal-Ceramic Interfaces, edited by Riihle, M. and Evans, A. G. (Pergamon Press, New York, 1990), p. 129.Google Scholar
11. Kozuka, Z., Yasugi, S., Nakajima, W., and Moriyama, J., Denkikagaku, 34, 35 (1966).Google Scholar