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Thermodynamical Estimations on the Amount of Liquid Phase During Reaction Synthesis of Nickel-Aluminides

Published online by Cambridge University Press:  22 February 2011

Seiji Miura
Affiliation:
Precision and Intelligence Laboratory, Tokyo Institute of Technology, Yokohama 226, Japan.
Yoshinao Mishima
Affiliation:
Precision and Intelligence Laboratory, Tokyo Institute of Technology, Yokohama 226, Japan.
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Abstract

The amounts of intermetallic compounds and liquid phase are estimated as a function of temperature during reaction syntheses for Ni–Al binary alloys having arbitrary compositions under adiabatic conditions. It is assumed that the phases that would present during the process are only those appearing in the equilibrium binary phase diagram. Calculations are done by using available data on heat of formation of intermetallic compounds and those on enthalpy of liquid phase. The results obtained arc discussed in view of the estimation and control of the amount of liquid phase, which is significant for the densification and shape change of materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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References

1. Gcrman, R.M., Bose, A. and Stoloff, N.S., High Temperature Ordered Intermetallic Alloys III, ed. by Liu, C.T., Taub, A.I., Stoloff, N.S. and Koch, C.C.. MRS Symposium Proceedings, vol. 133, 403, Pittsburgh, (1989).Google Scholar
2. Munir, Z.A., Am. Ceram. Soc. Bull., 67, 342 (1988).Google Scholar
3. Hlavacek, V., Am. Ceram. Soc. Bukk., 70, 240 (1991).Google Scholar
4. Naiborodenko, Yu.S., Itin, V.I. and Savitskii, K.V., Soviet Physics J., 11 No. 10, 19(1968).Google Scholar
5. Philpot, K.A., Munir, Z.A. and Holt, J.B., J. Mat. Sci., 22, 159 (1987).Google Scholar
6. Nishimura, C., Amano, M. and Kainuma, Y., Mat. Trans., JIM, 31, 471 (1990).Google Scholar
7. Mabuchi, H., Harada, K., Tsuda, H. and Nakayama, Y., ISIJ international, 31, 1272 (1991).Google Scholar
8. Dahms, M., Seeger, J., Smarsly, W. and Wildhagen, B., ISIJ international, 31, 1093(1991).Google Scholar
9. Yoon, E.H., Hwang, S.K., Kim, Y.J. and Chung, H.S., Proceedings of International Symposium on Intermetallic compounds-Structure and Mechanical Properties-(JIMIS6), ed.by Izumi, O., The Japan Inst. Metals, Sendai, Japan, 935 (1991).Google Scholar
10. Nishimura, C. and Liu, C.T., Scripta MET. MAT., 26, 381, (1992).Google Scholar
11. Wu, K.H. and Liu, C.T., High Temperature Ordered Intermetallic Alloys V, eds. Baker, I., Darolia, R.. Whittenberger, J.D. and Yoo, M.H.. MRS Symposium Proceedings, vol. 288, 841, Pittsburgh, (1993).Google Scholar
12. Miura, S. and Liu, C.T., Intermetallies, 2, 297 (1994).Google Scholar
13. Nuppmann, W.J., Z. Metallkde., 70, 792 (1979).Google Scholar
14. Hwang, K.S., German, R.M. and Lencl, F.V., Met. Trans. A, 18A. 11 (1987).Google Scholar
15. German, R.M., The Int. J. Powder Met., 26, 23 (1990).Google Scholar
16. Bose, A., Moore, B., German, R.M. and Stoloff, N.S., J.Metals, 40, No.9, 14 (1988).Google Scholar
17. Janssen, M.M. P. and Rieck, G.D., Trans. Met. Soc. AIME, 239, 1372 (1967).Google Scholar
18. Jung, S.B., Minamino, Y., Yamane, T. and Saji, S., J.Mat. Sci. Letter, 12, 1684, (1993).Google Scholar
19. Hultgren, R. et al., “Selected Values of the Thermodynamic Properties of Binary Alloys”, ASM, Metals Park, Ohio, (1973).Google Scholar
20. Barin, I., Knackc, O. and Kubaschewski, O.., “Thermochemical properties of inorganic substances, supplement”, Verlag Stahleisen m.b.H., Dusseldorf, (1977).Google Scholar
21. Pasurel, A., Hicter, P., Mayou, D. and Cyrot-Lackmann, F., Scripta Met., 17, 841 (1983).Google Scholar
22. Kubaschewski, O., Alcock, C.B. and Spencer, P.J.., “Materials Thermochemistry, 6th ed.”, Pergamon Press, Oxford, (1993).Google Scholar
23.Selected powder diffraction data for metals and alloys–, eds. Weissmann, S. et al., JCPDS International Centre for Diffraction Data, Pennsylvania, U.S.A. (1978).Google Scholar
24.Atlas of crystal structure types for intermetallic phases”, eds. Daams, J.L.C., Villars, P. and van Vucht, J.H.N., ASM International, Materials park, Ohio. (1991).Google Scholar