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Thermal effects on the Raman spectra of nanodiamonds

Published online by Cambridge University Press:  22 March 2011

Marc Chaigneau ,
Hugues A. Girard ,
Jean-Charles Arnault  and
Razvigor Ossikovski
Marc Chaigneau
Affiliation:
LPICM, Ecole Polytechnique, CNRS, 91128 Palaiseau, France
Hugues A. Girard
Affiliation:
PMC, Ecole Polytechnique, CNRS, 91128 Palaiseau, France CEA, LIST, Diamond Sensors Laboratory, F91191 Gif-sur-Yvette, France
Jean-Charles Arnault
Affiliation:
CEA, LIST, Diamond Sensors Laboratory, F91191 Gif-sur-Yvette, France
Razvigor Ossikovski
Affiliation:
LPICM, Ecole Polytechnique, CNRS, 91128 Palaiseau, France
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Abstract

We report on the influence of the laser heating effect, potentially present in a Raman scattering experiment, on the behaviour of carbon phonon lines in the spectra of nanodiamond particles. Aside from the laser power used in the experiment, the extent of the thermal effect in question depends also on the nanodiamonds origin (obtained through detonation and high pressure high temperature techniques) as well as on the nanoparticles size. Laser heating should be properly taken into account when discussing Raman spectra of carbonaceous species, in particular, prior to addressing peak assignment and possible quantum confinement effects.

Keywords

diamondRaman spectroscopynanoscale
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1282: Symposium A – Diamond Electronics and Bioelectronics—Fundamentals to Applications IV , 2011 , mrsf10-1282-a04-03
Copyright
Copyright © Materials Research Society 2011

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