Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-25T18:25:06.040Z Has data issue: false hasContentIssue false

Theoretical and Empiriical Modeling of the Rheology of Fresh Cement Pastes

Published online by Cambridge University Press:  15 February 2011

Gebran N. Karam*
Affiliation:
Department of Civil and Environmental Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
Get access

Abstract

The most important property of cements and concretes after strength is the workability, which is controlled by the rheological characteristics of the mix. Theoretical modeling having proved complicated and in some cases mathematically untractable, cement specialists have concentrated on empirical based models for the last two decades. The major theoretical contributions to date on the properties of colloidal and concentrated suspensions are summarized and a general framework for theoretical modeling of cement viscosity is established. The empirical modeling and the experimental investigation of the rheological properties of fresh cements are reviewed and discussed. A semi-empirical model is proposed and its validity tested in the interpretation of some published experimental results.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Shaughnessy, R. and Clark, P.E., Cem. Cone. Res. 18, 327341 (1988)Google Scholar
2. Tattersall, G.H. and Banfill, P.F.G., The Rheology of Fresh Concrete, (Pitman Advanced Publishing Program, 1983)Google Scholar
3. Chatterji, S., Cem. Cone. Res. 16, 967970 (1986)Google Scholar
4. Jones, T.E.R. and Taylor, S., Mag. Cone. Res. 29 (101), 207212 (1977)Google Scholar
5. Berg, W. vom, Mag. Cone. Res. 31 (109), 211216 (1979)Google Scholar
6. Banfill, P.F.G., Mag. Cone. Res. 43 (154), 1321 (1991)Google Scholar
7. Murata, J. and Kikukawa, H., ACI Mat. J. 89 (3), 230237 (1992)Google Scholar
8. Wessel, R. and Ball, R.C., Phys. Rev. A 46 (6), (1992)Google Scholar
9. Michaels, A.S. and Bolger, J.C., I & EC Fundam. 1, 153–162 (1962)Google Scholar
10. Thomas, D.G., Am. Inst. Chem. Eng. J. 9 (3), 310316 (1963); 10 (4), 517–523 (1964)Google Scholar
11.J.S. O'Brien and Julien, P.Y., J. Hyd. Eng. ASCE 114 (8), 877887 (1988)Google Scholar
12. Sybertz, F. and Reick, P., in Rheology of Fresh Cement and Concrete, edited by Banfill, P.F.G. (E.& F.N. Spon, Chapman and Hall, 1991) pp.1322 Google Scholar
13. Burgers, J.M., Second Report on Viscosity and Plasticity, (Nordemann, New York, 1938)Google Scholar
14. Vand, V., J. Phys. Coll. Chem. 52 (2), 277299 (1948)Google Scholar
15. Walpole, L.J., Quart. J. Mech. Appl. Math. 25 (2), 153160 (1972)Google Scholar
16. Batchelor, G.K. and Green, J.T., J. Fluid Mech. 56 (3), 401427 (1972)Google Scholar
17. Willis, J.R. and Acton, J.R., J. Mech. Appl. Math. 29 (2), 163177 (1976)Google Scholar
18. Chen, H.S. and Acrivos, A., Int. J. Solids Struct. 14, 349364 (1978)Google Scholar
19. Roscoe, R., Brit. J. Appl. Phys. 3, 267269 (1952)Google Scholar
20. Krieger, I.M., Adv. Colloid Int. Sc. 3, 111136 (1972)Google Scholar
21. Locat, J. and Demers, D., Can. Geotech. J. 25, 799806 (1988)Google Scholar
22. Joshi, R.C. and Nagaraj, T.S., J. Mats. Civ. Eng. ASCE 2 (3), 128135 (1990)Google Scholar