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Temperature Dependence Study of Gas Permeability in Metal Doped Composite Polymeric Membranes

Published online by Cambridge University Press:  26 February 2011

Yogesh Kumar Vijay ,
Anil Kumar Jain ,
Naveen Kumar Acharya ,
Kamlendra Awasthi  and
Vaibhav Kulshrestha
Yogesh Kumar Vijay
Affiliation:
[email protected], University of Rajasthan, Jaipur, Department of Physics, 9-10, Vigyan Bhawan, Department of Physics, University of Rajasthan, Jaipur, India-302 004, Jaipur, 302004, India, +91-141-3290402, +91-141-2707728
Anil Kumar Jain
Affiliation:
[email protected], University of Rajasthan, Jiapur, Department of Physics, 9-10, Vigyan Bhawan, JAIPUR, 302004, India
Naveen Kumar Acharya
Affiliation:
[email protected], University of Rajasthan, Jiapur, Department of Physics, 9-10, Vigyan Bhawan, JAIPUR, 302004, India
Kamlendra Awasthi
Affiliation:
[email protected], University of Rajasthan, Jiapur, Department of Physics, 9-10, Vigyan Bhawan, JAIPUR, 302004, India
Vaibhav Kulshrestha
Affiliation:
[email protected], University of Rajasthan, Jiapur, Department of Physics, 9-10, Vigyan Bhawan, JAIPUR, 302004, India
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Abstract

Polycarbonate (PC) membrane and PC based hydrogen active intermetallic compound Fe0.5Ti0.5 particles doped composite membrane have been prepared by solution cast method. The membranes have been characterized by H2 and CO2 permeability and selectivity measurements with increasing temperature. Higher gas permeation has been observed with increasing temperature. In case of doped composite membrane H2/CO2 gas pair selectivity first increases then decreases with temperature whereas in case of pure PC it decreases with temperature. The effect of doping increases the activation energies for permeation of H2 and CO2 in the doped membrane in comparison to pure PC. Doping was found to suppress plasticization effect in polycarbonate. The doped membrane was analyzed by optical micrograph and XRF study.

Keywords

gas chromatographypolymercomposite
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 973: Symposium BB – Mobile Energy , 2006 , 0973-BB04-16
Copyright
Copyright © Materials Research Society 2007

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References

REFERENCES

1 Veziroglu, T. N., Chem. Ind., 53, 383 (1993).Google Scholar
2 Freeman, B. D., Macromolecules 32, 375 (1999).Google Scholar
3 Mahajan, R., Zimmerman, C. M., Koros, W. J., in Polymer Membranes for Gas and Vapor Separation:Chemistry and Materials Science, Edited by Freeman, B. D., Pinnau, I. (American Chemical Society, 1999), pp. 277–286 Google Scholar
4 Merkel, T. C., Freeman, B. D., Spontak, R. J., He, Z., Pinnau, I., Meakin, P., Hill, A. J., Science, 296, 519 (2002).Google Scholar
5 Asanuma, H., Tosima, N., J. Polym. Sci. Polym. Chem. Ed. 28, 907 (1990).Google Scholar
6 Toshima, N., in Polymers for Gas Separation, edited by Toshima, N. (VCH Publisher, 1991) pp.10–11 Google Scholar
7 Reilly, J. J., Wiswau, R. H., Inorg. Jr., Chem. 13, 218 (1974).Google Scholar
8 Vijay, Y. K., Wate, S., Acharya, N. K., Garg, J.C., International J. of Hydrogen Energy, 27, 905 (2002).Google Scholar
9 Koros, W. J., Coleman, M. R., Walker, D. R. B., Annu. Rev. Mater. Sci. 22, 47 (1992).Google Scholar