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A Technique for In—Situ Detection of Growth Dislocations
Published online by Cambridge University Press: 28 February 2011
Abstract
A formidable obstacle to develop the optimal conditions for growing dislocation—free crystals has been the lack of a direct technique to monitor the perfection of the solid/liquid (S/L) interface during growth. Recently we have developed a technique which detects, in—situ, the emergence of dislocation(s) at the crystallization front. This novel technique is based on the thermoelectric principles, and utilizesthe dependence of the Seebeck emf generated across the S/L interface upon the interface temperature, crystal orientation, and dopant concentration. The technique was used to directly measure the S/L interface temperature during growth of Ga and In—doped Ga. For the latter, the technique also shows the breakdown (instability) of the faceted interface, which leads to the entrapment of the In—rich bands. The applicability of the technique to monitor defect formation during crystal growth processes such as thin film zone, Czochralski, or liquid phase epitaxy will be discussed.
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- Copyright © Materials Research Society 1986