Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-29T07:24:52.906Z Has data issue: false hasContentIssue false

Synthesis of Soluble Carcerands

Published online by Cambridge University Press:  31 January 2012

Jiménez-Gutiérrez I. Eddy
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C. P. 04510, México D. F.
Sánchez-Montes K. Erika
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C. P. 04510, México D. F.
Cortez-Maya Sandra
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C. P. 04510, México D. F.
Flores-Rojas Gabriel
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C. P. 04510, México D. F.
Martínez-García Marcos
Affiliation:
Instituto de Química, Universidad Nacional Autónoma de México, Ciudad Universitaria, Circuito Exterior, Coyoacán, C. P. 04510, México D. F.
Get access

Abstract

An efficient synthetic route for the synthesis of carcerands derived from tetramethylchlorocavitands and its tetraesters derivative were synthesized. A large-scale preparation was achieved in good yield. These carcerands are in bridging unit between oxygen atoms, i.e. contains a 3,5 dihydroxybencyl alcohol units. 1H, and 13C NMR in solution, FTIR, UV-vis spectroscopy, MS-FAB+ spectrometry and elemental analysis confirmed the structure of this carcerands.

Type
Articles
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Kuhnert, N., Le-Gresley, A., Tetrahedron Lett. 49, 1274 (2007).Google Scholar
2. Jain, V. K., Kanaiya, P. H., Russ. Chem. Rev. 80, 75 (2011).Google Scholar
3. Liu, X., Warmuth, R., Nat. Prot. 2, 1288 (2007).Google Scholar
4. Pietraszkiewicz, M., Prus, P., Pietraszkiewicz, O., Tetrahedron. 60, 10747 (2004).Google Scholar
5. El Moll, H., Sémeril, D., Matt, D., Youinou, M., Toupet, L., Org. Biomol. Chem. 7, 495 (2009).Google Scholar
6. Dueno, E. and Bisht, K., Tetrahedron. 60, 10859 (2004).Google Scholar
7. Bradley, G. W. and Lawton, M. J. Org. Chem. 75, 8531(2010).Google Scholar