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Synthesis of Hydrotalcite-Like Precursor Compounds MgCo(11) Co(111).-HTlcs

Published online by Cambridge University Press:  15 February 2011

H.C. Zeng ,
Z.P. Xu  and
M. Qian
H.C. Zeng
Affiliation:
Department of Chemical and Environmental Engineering, Faculty of Engineering National University of Singapore, 10 Kent Ridge Crescent, Singapore119260Email address: [email protected]
Z.P. Xu
Affiliation:
Department of Chemical and Environmental Engineering, Faculty of Engineering National University of Singapore, 10 Kent Ridge Crescent, Singapore119260
M. Qian
Affiliation:
Department of Chemical and Environmental Engineering, Faculty of Engineering National University of Singapore, 10 Kent Ridge Crescent, Singapore119260
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Abstract

Precursor compounds of MgCo(11)Co(111)-HTlcs for Mg-Co oxide catalysts have been synthesized by coprecipitation in an ammoniacal solution and hydrothermal treatments under various O2/N2 atmospheres. Using elemental analysis (EA) and redox titration, it is found that about 23% of original Co2+ are oxidized to Co+3, resulting in formation of hydrotalcite-like (HTI) structure. The anion (NO3) intercalation increases with the rise in O2 partial pressure. X-ray diffraction pattern shows a conversion from brucite-like to HTl structures with increase of O2 partial pressure. It is found that thermal stability of the HTl-compounds is proportional to the Mg content. Higher specific surface areas are observed for decomposed products with low Co/Mg ratio. A trace amount of CO3O4 is also detected by FTIR for samples synthesized under high O2 partial pressures, which can be attributed to a deeper oxidation of Co2+.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 549: Symposium FF – Advanced Catalytic Materials - 1998 , 1998 , 85
Copyright
Copyright © Materials Research Society 1999

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