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Synthesis of Hydraulically Active Calcium Silicates Produced by Combustion Methods

Published online by Cambridge University Press:  27 March 2015

Juan C. Restrepo ,
Andrés Chavarriaga ,
Oscar J. Restrepo  and
Jorge I. Tobón
Juan C. Restrepo
Affiliation:
Universidad Nacional de Colombia, Facultad de Arquitectura, Medellín, Colombia.
Andrés Chavarriaga
Affiliation:
Universidad Nacional de Colombia, Facultad de Minas, Medellín, Colombia.
Oscar J. Restrepo
Affiliation:
Universidad Nacional de Colombia, Facultad de Minas, Medellín, Colombia.
Jorge I. Tobón
Affiliation:
Universidad Nacional de Colombia, Facultad de Minas, Medellín, Colombia.
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Abstract

Portland cement is synthesized from a mixture of limestone and clay at high temperature (1450 °C) via a conventional process (solid-phase synthesis), in which partial fusion of raw materials and the formation of clinker nodules are produced. The clinker is mixed with a small percentage of gypsum and ground together to make the cement. This synthesis process holds the cement industry accountable for 5–8% of global anthropogenic CO2 emissions. The production of a ton of cement emits between 0.62 and 0.97 tons of CO2 into the atmosphere, depending on the processing plant. Furthermore, the use of fossil fuels in cement production is another important factor in the environmental impact of this industry. The production of 1 ton of clinker consumes approximately 5.86 GJ per tons of clinker produced in wet processes and 3.35 GJ per tons of clinker produced by dry process. Some researches have reported the possibility to obtain silicate and aluminate cements by alternative synthesis methods, which optimize both time and temperature, such as Pechini method, sol-gel method and microwave assisted method. The combustion methods, another alternative, are chemical redox processes in which the use of chemical precursors and organic fuels at high temperature generate a self-sustaining fastwave. The said wave is characterized by the fact that once the initial exothermic reaction starts, it generates a reaction wave (0.1–10 cm/s) at high temperature (1000–3000 °C) that propagates, in a self-sustaining way, through the heterogeneous mixture which leads to the formation of the solid material. For this reason, and the irreplaceable role of cement in the construction industry, this paper shows the advances in the production of silicates, similar to those found in the Portland cement, by combustion synthesis method.

This paper shows the production of calcium silicates similar to the silicates of Portland cement, by combustion synthesis. Thermal analysis and XRD techniques were used to compare the syhthetized silicates with alite and belite of Portland cement.

Keywords

compositeadditiveschemical composition
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1768: Symposium 6D – Concrete with Smart Additives and Supplementary Cementitious Materials to Improve Durability and Sustainability of Concrete Structures. , 2015 , imrc2014-6d-008
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

Habert, G., Billard, , Rossi, P., Chen, C. and Roussel, N. Cement production technology improvement compared to factor 4 objectives. Cem. and Conc. Research. 2010.CrossRefGoogle Scholar
Chrysafi, R., Perraki, Th. and Kakali, G. Sol–gel preparation of 2CaO.SiO2. Journal of the European Ceramic Society. Vol. 27, pag. 1707–1710. 2007.CrossRefGoogle Scholar
Scrivener, K. and Kirkpatrick, R. Innovation in use and research on cementitious material. Cement and Concrete Research. Vol. 38, pag. 128–136. 2008.CrossRefGoogle Scholar
International Cement Rewiev, 2010. http://www.cemnet.com/publications/international-cement-review Google Scholar
Damineli, B., Kemeid, L., Aguiar, F.P. and John, Vanderley. Measuring the eco-efficiency of cement use□ S. Department of Construction Engineering. Escola Politécnica, University of São Paulo, Brazil. Cement and Concrete Research, 2010.Google Scholar
Taylor, H.F.W. Cement Chemistry. 2nd ed. Thomas Telford. 1997.CrossRefGoogle Scholar
Dunstetter, F., Noirfontaine, M.N. and Courtial, M. Polymorphism of tricalcium silicate, the mayor compound of portland cement clinker. Cem. and Conc. Research. 2006.CrossRefGoogle Scholar
Hong, S-H. and Young, J.F. Hydration Kinetics and Phase Stability of Dicalcium Silicate Synthesized by the Pechini Process. J. Am. Ceram. Soc. Vol. 82, pag. 1681–86. 1999.CrossRefGoogle Scholar
Gaki, A., Chrysafi, R. and Kakali, G. Chemical synthesis of hydraulic calcium aluminate compounds using the Pechini technique. Journal of European Ceramic Society. 2007.CrossRefGoogle Scholar
Roy, D.M. and Oyefesobi, S.O. Preparation of very reactive Ca2SiO4 powder. Journal American Ceramic Society. Vol. 60, pag. 178–180. 1977.CrossRefGoogle Scholar
Stephan, D. andy Wilhelm, P. Synthesis of Pure Cementitious Phases by Sol-Gel Process as Precursor. Garching bei München, Anorganisch-chemisches. 2004.CrossRefGoogle Scholar
Page, C.H., Thombare, C.H., Kamat, R.D. and Chatterjee, A.K. Development of Sol–Gel technology for cement manufacture. Ceram. Trans. Vol. 16, pag. 643–660. 1991.Google Scholar
Li, H., Agrawal, D.K., Cheng, J. and Silsbee, M.R. Formation and hidration of C3S prepard by microwave and conventional sintering. Cement and Concrete Research. 1999.CrossRefGoogle Scholar
Li, H., Agrawal, D.K., Cheng, J. and Silsbee, M.R. Microwave sintering of sulphoaluminate cement with utility wastes. Cement and Concrete Research. Vol. 31, 2001.CrossRefGoogle Scholar
Long, S., Yan, C. and Dong, J. Microwave-promoted burning of Portland cement clinker. Cement and Concrete Research. Vol. 32, pag. 17–21. 2002.CrossRefGoogle Scholar
Zapata, A. and Bosch, P. Low temperature preparation of belitic cement clinker. Journal of the European Ceramic Society. Vol. 29, pag. 1879–1885. 2009.CrossRefGoogle Scholar
Huang, X-H. and Chang, J. Low-temperature synthesis of nanocrystalline b-dicalcium silicate with high specific surface area. Journal of Nanoparticle Research. 2007.CrossRefGoogle Scholar
Fumo, D.A., Morelli, M.R. and Segadães, A.M. Combustion Synthesis Of Calcium Aluminates. Materials Research Bulletin. Vol. 31, pag. 1243–1255.1996.CrossRefGoogle Scholar
Gartner, E. Industrial Interesting Approaches to low CO2 Cements. Cement and Concrete Research. Vol. 34, pag. 1489–1498. 2004.CrossRefGoogle Scholar
Van den Heede, P. and De Belie, N. Environmental impact and life cycle assessment of traditional and ‘green’ concretes: Literature review and theoretical calculations. Cement & Concrete Composites. Vol. 34, pag. 431–442. 2012.CrossRefGoogle Scholar
Mehta, P.K. Reducing the Environmental Impact of Concrete-Concrete can be durable and environmentally friendly. Concrete - International 5. 2001.Google Scholar
Roskovic, R. and Bjegovic, D. Role of mineral additions in reducing CO2 emission. Cement and Concrete Research. Vol. 35, pag. 974–978. 2005.CrossRefGoogle Scholar
Wesselsky, A. andy Jensen, O.M. Synthesis of pure Portland cement phases. Cement and Concrete Research. Vol. 39, pag. 973–980. 2009.CrossRefGoogle Scholar
Raab, B. & Pöllmann, H. Synthesis of pure cement phases by different synthesis methods. International Conference on Calcium Aluminate Cements. France. 2008.Google Scholar
Mossino, P. Review:□ Some aspects in self-propagating high-temperature synthesis. Ceramics International. Vol. 30, pag. 311–332. 2004.CrossRefGoogle Scholar
Brinker, C.F. and Scherrer, G.W. The Physics and Chemistry of Sol-Gel Processing. Academic press, inc. 1990.Google Scholar
Stoyanova, T. Síntesis no Convencional y Caracterización de Pigmentos Cerámicos Basados en Cromo. Tesis Doctoral 2009, Universitat Jaume I de Castellon, España.Google Scholar
Kakihana, M. Sol-Gel Preparation of High Temperature Superconducting Oxides. J. Sol-Gel Sci.Tecnol. Vol. 6, pag. 7–55. 1996.CrossRefGoogle Scholar
Merzhanov, A.G. and Borovinskaya, I.P. Patent: Self-propagated high-temperature synthesis of refractory inorganic compounds", Doklady Akademii Nauk SSSR. 1972.Google Scholar
Mukasyan, A.S., Epstein, P. and Dinka, P. Solution combustion synthesis of nanomaterials. Proceedings of the Combustion Institute. Vol. 31. 2007.CrossRefGoogle Scholar
Montoya, J.F., Chavarriaga, E.A., Restrepo, J.C. y Restrepo, O.J. Pigmentos Cerámicos con Estructura Espinela ZnCr2O2 y CuCr2O4 sintetizados por la ruta de reacción en micelas normales. Revista Colombiana de Materiales. Nro. 5, pag. 278–283. 2014.Google Scholar
Jaramillo, L., Montoya, J.F., Chavarriaga, E.A., Restrepo, J.C. y Restrepo, O.J. Fabricación del Pigmento Cerámico ZnCr2O4 tipo Espinela por Métodos no Convencionales. Revista Colombiana de Materiales. Nro. 5, pag. 284–289. 2014.Google Scholar
Varma, A., Mukasyan, A.S., Deshpande, K., Pranda, P. and Erii, P. Mat. Res. Soc. Symp. Proc. 800 113–124. 2003.CrossRefGoogle Scholar
Pederson, L.R. US patent number: 5,114,702. 1992.Google Scholar
Chick, L.A., Pederson, L.R., Maupin, G.D., Bates, J.L., Thomás, L.E and Exarhos, G.J. Materials Letters. Vol. 10, pag. 6. 1990.CrossRefGoogle Scholar
Cruz, D. and Bulbulian, S. Synthesis of lithium silicate tritium breeder □powders by modified combustion method. J. Nucl. Mater. Vol. 4, pag. 262– □265. 2003.CrossRefGoogle Scholar
Burgos-Montes, O., Moreno, R., Colomer, M.T. and Fariñas, J.C. Synthesis of mullite powders through a suspension combustion process. J. Am. Ceram. Soc. 2006.Google Scholar
Mendoza, O and Tobón, J.I. An alternative thermal method for identification of pozzolanic activity in Ca(OH)2/pozzolan pastes. J Therm Anal Calorim. DOI 10.1007/s10973-013-2973-y. 2013.Google Scholar