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Synthesis of Hybrid Inorganic-Organic Sol-Gel Coatings for Optics

Published online by Cambridge University Press:  21 February 2011

B. Lebeau ,
C. Guermeur  and
C. Sanchez
B. Lebeau
Affiliation:
Laboratoire de Chimie de la Matière Condensée, URA CNRS 1466, Université Pierre et Marie Curie, Paris, FRANCE.
C. Guermeur
Affiliation:
Laboratoire de Chimie de la Matière Condensée, URA CNRS 1466, Université Pierre et Marie Curie, Paris, FRANCE.
C. Sanchez
Affiliation:
Laboratoire de Chimie de la Matière Condensée, URA CNRS 1466, Université Pierre et Marie Curie, Paris, FRANCE.
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Abstract

The synthesis of transparent hybrid organic-inorganic coatings obtained from condensation between alkoxysilane containing grafted dyes (azo dyes or phthalocyanines) and metal alkoxides precursors has been performed. The Red 17 azo dye, known for its high second order polarisability, was bonded to the silicon oxide network following two procedures: a silylation reaction between Red 17 and triethoxysilane; a coupling reaction between Red 17 and 3-isocyanatopropyltriethoxysilane. Silicon phthalocyanines (known for their third order polarisability and inverse saturable absorption properties) were incorporated into the silicon oxide network by a silylation reaction. Phthalocyanine doped transparent hybrid organic-inorganic coatings were obtained from condensation between diethoxymethylsilane and zirconium propoxide precursors.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 346: Symposium N – Better Ceramics Through Chemistry VI , 1994 , 315
Copyright
Copyright © Materials Research Society 1998

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References

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