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Synthesis and site-selective photoluminescence property of Ca8La2(PO4)6O2: Ce3+

Published online by Cambridge University Press:  27 March 2014

Ge Zhu ,
Yurong Shi ,
Masayoshi Mikami ,
Yasuo Shimomura  and
Yuhua Wang
Ge Zhu
Affiliation:
Department of Materials Science, School of PhysicalScience and Technology, Lanzhou University, Lanzhou, 730000, China
Yurong Shi
Affiliation:
Department of Materials Science, School of PhysicalScience and Technology, Lanzhou University, Lanzhou, 730000, China
Masayoshi Mikami
Affiliation:
Mitsubishi Chemical Group Science and Technology Research Center, Yokohama 227-8502, Japan
Yasuo Shimomura
Affiliation:
Mitsubishi Chemical Group Science and Technology Research Center, Yokohama 227-8502, Japan
Yuhua Wang*
Affiliation:
Department of Materials Science, School of PhysicalScience and Technology, Lanzhou University, Lanzhou, 730000, China
*
*Email: [email protected]
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Abstract

A series of Ce3+ doped Ca8La2(PO4)6O2 phosphors with tunable emission were successfully synthesized by traditional solid state reaction. The crystal structure and photoluminescence properties were studied through X-ray diffraction, photoluminescence excitation and emission spectra. The results indicated that Ca8La2(PO4)6O2:Ce3+ exhibited color-tunable emission due to the 5d-4f transitions of Ce3+ ions under different wavelength excitation. The optimal doping content of Ce3+ ions in Ca8La2(PO4)6O2 was found to be 5 mol%. The site-selective photoluminescence property and the reason for red-shift of the emission band along with Ce3+ content and the excitation wavelength were also studied in detail.

Keywords

luminescenceoptical propertiesdisplay
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1592: Symposium I – Rare Earth Doped Advanced Materials for Photonic Applications , 2014 , jsapmrs13-1592-6391
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Liang, H. B., Zeng, Q., and Tian, Z. F., J. Electrochem. Soc. 154, J177 (2007).CrossRefGoogle Scholar
Zhang, J. H., Liang, H. B., and Su, Q., J. Phys. D: Appl. Phys. 42, 105110 (2009).CrossRefGoogle Scholar
Ryan, F. M. and Warren, R. W., J. Electrochem. Soc. 125, 1493 (1978).CrossRefGoogle Scholar
Boyer, L. and Carpena, J.,Solid State Ionics 95, 121 (1997).CrossRefGoogle Scholar
Schwarz, H., Z. Anorg. Chem. 29, 356 (1967).Google Scholar
Steinbruegge, K. B., Baldwin, G. D.,Appl. Phys. Lett. 25, 220 (1974).CrossRefGoogle Scholar
Li, G., Geng, D., Shang, M., Peng, C., Cheng, Z. and Lin, J., J. Mater. Chem. 21, 13334 (2011).CrossRefGoogle Scholar
Boulon, G., Collombet, A., Brenier, A., Cohen-Adad, M., Yoshikawa, A., Lebbou, K., Lee, J. and Fukuda, T., Adv. Funct. Mater. 11(4), 263 (2001).3.0.CO;2-M>CrossRefGoogle Scholar
Li, G. G., Geng, D. L., Shang, M. M., Zhang, Y., Peng, C., Cheng, Z. Y., and Lin, J., J. Phys. Chem. C 115(44), 21882 (2011).Google Scholar
Lin, J. and Su, Q., J. Mater. Chem. 5(8), 1151 (1995).CrossRefGoogle Scholar
Zhang, C. M., Huang, S. S., Yang, D. M., Kang, X. J., Shang, M. M., Peng, C. and Lin, J., J. Mater. Chem. 20(32), 6674 (2010).CrossRefGoogle Scholar
Zhu, G., Wang, Y. H., Ci, Z. P., Liu, B. L., Shi, Y. R. and Xin, S. Y., J. Electrochem. Soc. 158(8), J236 (2011).CrossRefGoogle Scholar
Yoshikawa, A., Kochurikhin, V. V., Futagawa, N., Shimamura, K., Fukuda, T., Journal of Crystal Growth 204, 302 (1999).CrossRefGoogle Scholar
Radiation Protection Dosimetry, 33, 151–154.Google Scholar
Ouenzerfi, R., El, , Panczer, G., Goutaudier, C., Cohen-Adad, M. T., Boulon, G., Trabelsi-Ayedi, M., Kbir-Ariguib, N., Opt. Mater. 16, 301 (2001).CrossRefGoogle Scholar
Shannen, R. D., Acta Crystallogr. A32, 751 (1976).CrossRefGoogle Scholar
Blasse, G. and Bril, A., J. Chem. Phys. 47, 5139 (1967).CrossRefGoogle Scholar
Liu, J., Lian, H., Shi, C. and Sun, J., J. Electrochem. Soc. 152(11), G880 (2005).CrossRefGoogle Scholar
Gong, Y., Wang, Y., Jiang, Z., Xu, X. and Li, Y., Materials Research Bulletin 44, 1916 (2009).CrossRefGoogle Scholar
Van Uitert, L. G., Lumin, J.. 29, 1 (1984).CrossRefGoogle Scholar
Robertson, J. M., Philips J. Res. 36, 15 (1981).Google Scholar
Rack, P. D. and Holloway, P. H., Mater. Sci. Eng. R. 21, 171 (1998).CrossRefGoogle Scholar