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Synthesis and Physicochemical Characterization of New Polythiophenes Based on Three Different Monomers

Published online by Cambridge University Press:  16 March 2015

Karla K. Guzmán-Rabadán ,
Marco A. Ramírez-Gómez ,
Marisol Güizado-Rodríguez ,
Jorge A. Guerrero-Álvarez ,
Víctor Barba ,
Miguel A. Basurto-Pensado ,
Rosario Galindo ,
Mario Rodríguez  and
José L. Maldonado
Karla K. Guzmán-Rabadán
Affiliation:
Centro de Investigación en Ingeniería y Ciencias Aplicadas (CIICAp), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Marco A. Ramírez-Gómez
Affiliation:
Centro de Investigación en Ingeniería y Ciencias Aplicadas (CIICAp), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Marisol Güizado-Rodríguez
Affiliation:
Centro de Investigación en Ingeniería y Ciencias Aplicadas (CIICAp), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Jorge A. Guerrero-Álvarez
Affiliation:
Centro de Investigaciones Químicas (CIQ), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Víctor Barba
Affiliation:
Centro de Investigaciones Químicas (CIQ), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Miguel A. Basurto-Pensado
Affiliation:
Centro de Investigación en Ingeniería y Ciencias Aplicadas (CIICAp), Universidad Autónoma del Estado de Morelos (UAEM). Av. Universidad No. 1001, Col. Chamilpa, C.P. 62209, Cuernavaca, Morelos, México.
Rosario Galindo
Affiliation:
Centro de Investigaciones en Óptica A.C., Loma del Bosque No. 115, Col. Lomas del Campestre, C.P. 37150, León, Guanajuato, México.
Mario Rodríguez
Affiliation:
Centro de Investigaciones en Óptica A.C., Loma del Bosque No. 115, Col. Lomas del Campestre, C.P. 37150, León, Guanajuato, México.
José L. Maldonado
Affiliation:
Centro de Investigaciones en Óptica A.C., Loma del Bosque No. 115, Col. Lomas del Campestre, C.P. 37150, León, Guanajuato, México.
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Abstract

The chemical synthesis of the copolymers poly(3-HT-co-EDOT-co-fluorene) and poly(3-HT-co-EDOT-co-TDR1) is reported. The first copolymer is derived of 3-hexylthiophene (3-HT), 3,4-ethylenedioxythiophene (EDOT) and 2,2'- (9,9-dioctyl-9H-fluorene-2,7-diyl) bisthiophene (fluorene). The second copolymer is derived of 3-hexylthiophene (3-HT), 3,4-ethylenedioxythiophene (EDOT) and (E)-2-(ethyl(4-((4-nitrophenyl)diazenyl)phenyl)amino)ethyl 2-(thiophen-3-yl)acetate (TDR1). Their physicochemical characterization by 1H NMR, FT-IR, DSC-TGA, GPC, UV-vis, cyclic voltammetry was carried out. These copolymers combine the high electron density and low oxidation potential of EDOT with the high charge mobility and processability of 3-HT. These are candidates for applications as active or barrier layer in electronic devices (bulk heterojuntion organic solar cells) or as functional membranes (e.g., sensors).

Keywords

chemical synthesispolymerizationmacromolecular structure
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1767: Symposium 5C – New Trends in Polymer Chemistry and Characterization , 2015 , pp. 57 - 62
Copyright
Copyright © Materials Research Society 2015 

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