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Synthesis and Nonlinearity of Triene Chromophores Containing the Cyclohexene Ring Structure

Published online by Cambridge University Press:  10 February 2011

Susan Ermer ,
Steven M. Lovejoy ,
Doris S. Leung ,
Hope Warren ,
Christopher R. Moylan  and
Robert J. Twieg
Susan Ermer
Affiliation:
Lockheed Martin Advanced Technology Center, O/HI-32, B/204, 3251 Hanover Street, Palo Alto, CA 94304
Steven M. Lovejoy
Affiliation:
Lockheed Martin Advanced Technology Center, O/HI-32, B/204, 3251 Hanover Street, Palo Alto, CA 94304
Doris S. Leung
Affiliation:
Lockheed Martin Advanced Technology Center, O/HI-32, B/204, 3251 Hanover Street, Palo Alto, CA 94304
Hope Warren
Affiliation:
Lockheed Martin Advanced Technology Center, O/HI-32, B/204, 3251 Hanover Street, Palo Alto, CA 94304
Christopher R. Moylan
Affiliation:
IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099
Robert J. Twieg
Affiliation:
IBM Almaden Research Center, 650 Harry Road, San Jose, CA 95120-6099
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Abstract

A series of conjugated donor-acceptor trienes in which the central double bond is incorporated into an unsaturated isophorone, verbenone or chromone ring has been synthesized. In each case, the donor group consists of an amine and an aromatic or heterocyclic ring system, and the acceptor is the dicyanomethylidene group. The nonlinear optical properties of each of the compounds has been measured and correlated with its structure. The dipole moments and molecular hyperpolarizabilities of these compounds, like those of other conjugated polyenes, are large enough to be used as the active components of electro-optic polymers. Unlike other donor-acceptor polyenes, however, these compounds exhibit the thermal stability required for such applications.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 243
Copyright
Copyright © Materials Research Society 1998

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