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Synthesis and Crystal Structure of C60 Complex with a Symmetrical Donor of 2,3,6,7,10,11- Hexamethoxytriphenylene (HMT)

Published online by Cambridge University Press:  16 February 2011

Long Y. Chiang ,
John W. Swirczewski  and
Keng S. Liang
Long Y. Chiang
Affiliation:
Center for Condensed Matter Sciences, National Taiwan University, Taipei, Taiwan
John W. Swirczewski
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
Keng S. Liang
Affiliation:
Corporate Research Laboratory, Exxon Research and Engineering Company, Annandale, New Jersey 08801
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Abstract

We have successfully synthesized single crystals of C60 fullerene complex with a symmetrical triplet donor of 2,3,6,7,10,11-hexamethoxytriphenylene (HMT). All spectroscopie data and analyses support the chemical composition of this complex as C60(HMT)2. Single crystals of C60(HMT)2 are, at 20±1 °C, cubic, space group Fd3c-Oh8 (No. 228) with a = 30.251(9) Å, α = 90.00°, V = 27682(30) Å3, Z = 16 (dcalcd = 1.476 gcm-3), and Ru (unweighted) = 0.098.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 85
Copyright
Copyright © Materials Research Society 1994

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