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Syntheses and Properties of k-Phase Organic Superconductors

Published online by Cambridge University Press:  25 February 2011

H. Hau Wang ,
K. D. Carlson ,
U. Geiser ,
A. M. Kini ,
A. J. Schultz ,
J. M. Williams ,
U. Welp ,
K. E. Darula ,
V. M. Hitsman  and
M. W. Lathrop
...Show all authors
H. Hau Wang
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
K. D. Carlson
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
U. Geiser
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
A. M. Kini
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
A. J. Schultz
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
J. M. Williams
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
U. Welp
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
K. E. Darula
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
V. M. Hitsman
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
M. W. Lathrop
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
L. A. Megna
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
P. R. Mobley
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
G. A. Yaconi
Affiliation:
Chemistry and Materials Science Divisions, Argonne National Laboratory, Argonne, IL 60439
J. E. Schirber
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
D. L. Overmyert
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
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Abstract

The syntheses and physical properties of K-(ET)2CU[N(CN)2]X (X = Br and Cl) are summarized. The K-(ET)2Cu [N(CN)2] Br salt is the highest Tc radical-cation based ambient pressure organic superconductor (Tc = 11.6 K), and the K-(ET)2CU [N(CN)2] C1 salt becomes a superconductor at even higher Tc under 0.3 kbar hydrostatic pressure (Tc = 12.8 K). The similarities and differences between K-(ET)2Cu[N(CN)2]Br and K-(ET)2CU(NCS)2 (TC = 10.4 K) are presented. The X-ray structures at 127 K reveal that the S-S contacts shorten between ET dimers in the former compound while the S-S contacts shorten within dimers in the latter. The differences in their ESR linewidth behavior is also explained in terms of the structural differences. A semiconducting compound, (ET)Cu[N(CN)2]2, isolated during K-(ET)2Cu[N(CN)2]Cl synthesis is also reported. The ESR measurements of the K-(ET)2Cu[N(CN)2]Cl salt indicate that the phase transition near 40 K is similar to the spin density wave transition in (TMTSF)2SbF6. A new class of organic superconductors, K-(ET)2CU2(CN)3 and K-(ET)2Cu2(CN)3.δBrδ, is reported with Tc's of 2.8 K (1.5 kbar) and 2.6 K (1 kbar), respectively.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 471
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Williams, J. M., Schultz, A. J., Geiser, U., Carlson, K. D., Kini, A. M., Wang, H. H., Kwok, W. -K., Whangbo, M. -H., Schirber, J. E., Science 252, 1501 (1991).Google Scholar
2. Hebard, A. F., Rosseinsky, M. J., Haddon, R. C., Murphy, D. W., Glarum, S. H., Palstra, T. T. M., Ramirez, A. P., Kortan, A. R., Nature 350, 600 (1991).Google Scholar
3. Rosseinsky, M. J., Ramirez, A. P., Glarum, S. H., Murphy, D. W., Haddon, R. C., Hebard, A. F., Palstra, T. T. M., Kortan, A. R., Zahurak, S. M., Makhija, A. V., Phys. Rev. Lett. 66, 2830(1991).Google Scholar
4. Holczer, K., Klein, O., Huang, S. M., Kaner, R. B., Fu, K. J., Whetten, R. L., Diederich, F., Science 252, 1154(1991).Google Scholar
5. Wang, H. H., Kini, A. M., Savall, B. M., Carlson, K. D., Williams, J. M., Lathrop, M. W., Lykke, K. R., Parker, D. H., Wurz, P., Pellin, M. J., Gruen, D. M., Welp, U., Kwok, W. K., Fleshier, S., Crabtree, G. W., Schirber, J. E., Overmyer, D. L., Inorg. Chem. 30, 2962 (1991).Google Scholar
6. Tanigaki, K., Ebbesen, T. W., Saito, S., Mizuki, J., Tsai, J. S., Kubo, Y., Kuroshima, S., Nature 352, 222(1991).Google Scholar
7. Iqbal, Z., Baughman, R. H., Ramakrishna, B. L., Khare, S., Murthy, N. S., Bornemann, H. J., Morris, D. E., Science 254, 826 (1991).Google Scholar
8. Beno, M. A., Wang, H. H., Kini, A. M., Carlson, K. D., Geiser, U., Kwok, W. K., Thompson, J. E., Williams, J. M., Inorg. Chem. 29, 1599 (1990).Google Scholar
9. Kahlich, S., Schweitzer, D., Heinen, I., Lan, S. E., Nuber, B., Keller, H. J., Winzer, K., Helberg, H. W., Solid State Commun. 80, 191 (1991).Google Scholar
10. Bechgaard, K., Mol. Cry st. Liq. Cryst. 22, 1 (1982).Google Scholar
11. Kikuchi, K., Saito, K., Ikemoto, I., Murata, K., Ishiguro, T., Kobayashi, K., Synth. Met. 27, B269 (1988).Google Scholar
12. Williams, J. M., Ferraro, J. R., Thorn, R. J., Carlson, K. D., Geiser, U., Wang, H. H., Kini, A. M., Whangbo, M. -H., Organic Superconductors; Synthesis. Structure. Properties and Theory (Prentice Hall, New Jersey, 1991).Google Scholar
13. Kini, A. M., Geiser, U., Wang, H. H., Carlson, K. D., Williams, J. M., Kwok, W. K., Vandervoort, K. G., Thompson, J. E., Stupka, D. L., Jung, D., Whangbo, M. -H., Inorg. Chem. 29, 2555 (1990).Google Scholar
14. Wang, H. H., Kini, A. M., Montgomery, L.K., Geiser, U., Carlson, K.D., Williams, J.M., Thompson, J.E., Watkins, D.M., Kwok, W.K., Welp, U., Vandervoort, K.G., Chem. Mater. 2, 482 (1990).Google Scholar
15. Zakhidov, A.A., Ugawa, A., Yakushi, K., Imaeda, K., Inokuchi, H., Khairullin, I.I., Khabibullaev, P.K., M2S-HTSC III, Kanazawa, Japan (1991), Physica C (in press).Google Scholar
16. Williams, J.M., Kini, A.M., Geiser, U., Wang, H.H., Carlson, K.D., Kwok, W.K., Vandervoort, K.G., Thompson, J.E., Stupka, D.L., Jung, D., Whangbo, M.-H., in Organic Superconductivity, edited by Kresin, V. and Little, W.L. (Plenum Press, New York, 1990), p. 39.Google Scholar
17. Urayama, H., Yamochi, H., Saito, G., Nozawa, K., Sugano, T., Kinoshita, M., Sato, S., Oshima, K., Kawamoto, A., Tanaka, J., Chem. Lett. 55 (1988).Google Scholar
18. Whangbo, M.-H., Novoa, J.J., Jung, D., Williams, J.M., Kini, A.M., Wang, H.H., Geiser, U., Beno, M.A., Carlson, K.D., in Organic Superconductivity, edited by Kresin, V. and Little, W.L. (Plenum Press, New York, 1990), p. 243.Google Scholar
19. Yu, R.C., Williams, J.M., Wang, H.H., Thompson, J.E., Kini, A.M., Carlson, K.D., Ren, J., Whangbo, M.-H., Chaikin, P.M., Phys. Rev. B: Condens. Matter 44, 6932 (1991).Google Scholar
21. Schirber, J.E., Venturini, E.L., Kini, A.M., Wang, H.H., Whitworth, J.R., Williams, J.M., Physica C (Amsterdam) 152, 157 (1988).Google Scholar
22. Schirber, J.E., Overmyer, D.L., Williams, J.M., Kini, A.M., Wang, H.H., Physica C (Amsterdam) 170, 231 (1990).Google Scholar
23. Umezawa, A., Malik, S.K., Crabtree, G.W., Wang, H.H., Montgomery, L.K., Carlson, K.D., Williams, J.M., M2S-HTSC III, Kanazawa, Japan (1991), Physica C (in press).Google Scholar
24. Kuznetsov, V.D., Metlushko, V.V., Epanechnikov, L.A., Makarov, E.F., Yagubskii, E.B., Kushch, N.D., Sverkhprovodimost' (KIAE) 4, 1413 (1991) [Superconductivity 4, 1303 (1991)].Google Scholar
25. Andraka, B., Jee, C.S., Kim, J.S., Stewart, G.R., Carlson, K.D., Wang, H.H., Crouch, A.V.S., Kini, A.M., Williams, J.M., Solid State Commun. 79, 57 (1991).Google Scholar
26. Andraka, B., Kim, J.S., Stewart, G.R., Carlson, K.D., Wang, H.H., Williams, J.M., Phys. Rev. B: Condens. Matter 40, 11345 (1989).Google Scholar
27. Wang, H.H., Carlson, K.D., Geiser, U., Kini, A.M., Schultz, A.J., Williams, J.M., Montgomery, L.K., Kwok, W.K., Welp, U., Vandervoort, K.G., Boryschuk, S.J., Strieby Crouch, A.V., Kommers, J.M., Watkins, D.M., Schirber, J.E., Overmyer, D.L., Jung, D., Novoa, J.J., Whangbo, M.-H., Synth. Met. 42, 1983 (1991).Google Scholar
28. Oshima, K., Urayama, H., Yamochi, H., Saito, G., Synth. Met. 27, A473 (1988).Google Scholar
29. Wosnitza, J., Crabtree, G.W., Wang, H.H., Carlson, K.D., Vashon, M.D., Williams, J.M., Phys. Rev. Lett. 67, 263 (1991).Google Scholar
31. Heidmann, C.-P., Müller, H., Biberacher, W., Neumaier, K., Probst, C., Andres, K., Jansen, A.G.M., Joss, W., Synth. Met. 42, 2029 (1991).Google Scholar
32. Sasaki, T., Sato, H., Toyota, N., M2S-HTSC III, Kanazawa, Japan (1991), Physica C (in DrCSS).Google Scholar
33. Geiser, U., Schultz, A.J., Wang, H.H., Watkins, D.M., Stupka, D.L., Williams, J.M., Schirber, J.E., Overmyer, D.L., Jung, D., Novoa, J.J., Whangbo, M.-H., Physica C (Amsterdam) 174, 475 (1991).Google Scholar
34. Wang, H.H., Beno, M.A., Carlson, K.D., Geiser, U., Kini, A.M., Montgomery, L.K., Thompson, J.E., Williams, J.M., in Organic Superconductivity, edited by Kresin, V. and Little, W.L. (Plenum Press, New York, 1990), p. 51.Google Scholar
35. Wang, H.H., Montgomery, L.K., Kini, A.M., Carlson, K.D., Beno, M.A., Geiser, U., Cariss, C.S., Williams, J.M., Venturini, E.L., Physica C (Amsterdam) 156, 173 (1988).Google Scholar
36. Forró, L., Sekretarczyk, G., Krupski, M., Schweitzer, D., Keller, H.J., Phys. Rev. B: Condens. Mattery, 35, 2501 (1987).Google Scholar
37. Wang, H.H., Geiser, U., Williams, J.M., Carlson, K.D., Kini, A.M., Mason, J.M., Perry, J.T., Charlier, H.A., Crouch, A.V.S., Heindl, J.E., Lathrop, M.W., Love, B.J., Watkins, D.M., Yaconi, G.A., Chem. Mater, (in submission).Google Scholar
38. Pedersen, H.J., Scott, J.C, Bechgaard, K., Phys. Rev. B 24, 5014 (1981).Google Scholar
39. Williams, J.M., Kini, A.M., Wang, H.H., Carlson, K.D., Geiser, U., Montgomery, L.K., Pyrka, G.J., Watkins, D.M., Kommers, J.M., Boryschuk, S.J., Strieby Crouch, A.V., Kwok, W.K., Schirber, J.E., Overmyer, D.L., Jung, D., Whangbo, M.-H., Inorg. Chem. 29, 3262 (1990).Google Scholar
41. Cramer, D.T., J. Phys. Chem. fil, 61, 1388 (1957).Google Scholar
42. Cramer, D.T. and Larson, A.C., Acta Crystallogr. 15., 397 (1962).Google Scholar
43. Geiser, U., Wang, H.H., Carlson, K.D., Williams, J.M., Charlier, H.A. Jr, Heindl, J.E., Yaconi, G.A., Love, B.J., Lathrop, M.W., Schirber, J.E., Overmyer, D.L., Ren, J., Whangbo, M.-H., Inorg. Chem. 30, 2586 (1991).Google Scholar
44. Sugano, T., Saito, G., Kinoshita, M., Phys. Rev. B: Condens. Matteria, 34, 117 (1986).Google Scholar
45. Komatsu, T., Nakamura, T., Matsukawa, N., Yamochi, H., Saito, G., Ito, H., Ishiguro, T., Kusunoki, M., Sakaguchi, K., Solid State Commun, (in press).Google Scholar
46. Kato, R., Kobayashi, H., Kobayashi, A., Moriyama, S., Nishio, Y., Kajita, K., Sasaki, W., Chem. Lett. 507 (1987).Google Scholar
47. Kurmoo, M., Talham, D. R., Pritchard, K. L., Day, P., Stringer, A. M., Howard, J. A. K., Synth. Met. 27, A177 (1988).Google Scholar
48. Mori, H., Hirabayashi, I., Tanaka, S., Mori, T., Inokuchi, H., Solid State Commun. 76, 35 (1990).Google Scholar
49. Carlson, K. D., Geiser, U., Kini, A. M., Wang, H. H., Montgomery, L. K., Kwok, W. K., Beno, A. M., Williams, J. M., Cariss, C. S., Crabtree, G. W., Whangbo, M. -H., Evain, M., Inorg. Chem. 27, 965 (1988).Google Scholar
50. Kwok, W. K., Welp, U., Carlson, K. D., Crabtree, G. W., Vandervoort, K. G., Wang, H. H., Kini, A. M., Williams, J. M., Stupka, D. L., Montgomery, L. K., Thompson, J. E., Phys. Rev. B: Condens. Matter 42, 8686 (1990).Google Scholar
51. Ito, H., Watanabe, M., Nogami, Y., Ishiguro, T., Komatsu, T., Saito, G., Hosoito, N., J. Phys. Soc. Jpn. (in press).Google Scholar
52. Le, L. P., Luke, G. M., Sternlieb, B. J., Wu, W. D., Uemura, Y. J., Wang, H. H., Kini, A. M., Williams, J. M., Stronach, C. E., M2S-HTSC III, Kanazawa, Japan (1991), Physica C (in press).Google Scholar
53. Uemura, Y. J., Le, L. P., Luke, G. M., Sternlieb, B. J., Brewer, J. H., Riseman, T. M., Saito, G., Yamochi, H., in Organic Superconductivity, edited by Kresin, V. and Little, W. L. (Plenum Press, New York, 1990), p. 23.Google Scholar
54. Takahashi, T., Kanoda, K., Saito, G., M2S-HTSC III, Kanazawa, Japan (1991), Physica C (in press).Google Scholar