Hostname: page-component-586b7cd67f-t7czq Total loading time: 0 Render date: 2024-11-29T07:50:35.806Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface Rotational Dynamics of Liquids Confined in Nanopores

Published online by Cambridge University Press:  10 February 2011

J.-P. Korb ,
L. Malier ,
F. Cros ,
Shu Xu  and
J. Jonas
J.-P. Korb
Affiliation:
Laboratoire de Physique de la Matière Condensée, CNRS, Ecole Polytechnique, 91128 Palaiseau, France
L. Malier
Affiliation:
Laboratoire de Physique de la Matière Condensée, CNRS, Ecole Polytechnique, 91128 Palaiseau, France
F. Cros
Affiliation:
Laboratoire de Physique de la Matière Condensée, CNRS, Ecole Polytechnique, 91128 Palaiseau, France
Shu Xu
Affiliation:
Department of Chemistry, University of Illinois, Urbana, Illinois 61801, U.S.A.
J. Jonas
Affiliation:
Department of Chemistry, University of Illinois, Urbana, Illinois 61801, U.S.A.
Get access

Abstract

2H NMR relaxation times of selectively deuterated polar molecules confined to a set of calibrated nanoporous silica glasses are reported. These experiments, combined with the consideration of different time scales in the theory of surface relaxation, show how confinement effects can provide detailed information on the rotational dynamics of temporarily adsorbed liquid layers in presence of biphasic fast exchange.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 464: Symposium FF – Dynamics in Small Confining Systems III , 1996 , 9
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Korb, J.-P., Malier, L., Cros, F., Xu, Shu, Jonas, J., Phys. Rev. Lett. 77, 2312 (1996).Google Scholar
[2] Korb, J.-P., Xu, Shu, Jonas, J., J. Chem. Phys. 98, 2411 (1993);Google Scholar
Korb, J.-P., Delville, A., Xu, Shu, Demeulenaere, G., Costa, G., Jonas, J., J. Chem. Phys. 101, 7074 (1994).Google Scholar
[3] Stapf, S., Kimmich, R., Seitter, R.O., Phys. Rev. Lett. 75, 2855 (1995).Google Scholar
[4] Mu, R. and Malhotra, V. M., Phys. Rev. B 46, 532 (1992);Google Scholar
Strange, J.H., Rahman, M., Smith, E.G., Phys. Rev. Lett. 71, 3589 (1993).Google Scholar
[5] Crawford, G.P., Yang, D.K., Zumer, S., Doane, J.W., Phys. Rev. Lett. 66, 723 (1991).Google Scholar
[6] Liu, G., Li, Y., Jonas, J., J. Chem. Phys. 95, 6892 (1991).Google Scholar
[7] Abragam, A., “The Principles of Nuclear Magnetism”, The Clarendon Press, Oxford, 1961.Google Scholar
[8] Bak, B.; J. Org. Chem. 21, 797 (1956);Google Scholar
Kintzinger, J.P., Mol. Phys. 30, 673 (1975).Google Scholar
[9] Huntress, W.T., J. Chem. Phys. 48, 3524 (1968).Google Scholar
[10] Brown, M., J. Chem. Phys. 77, 1576 (1982).Google Scholar
[11] Xu, Shu and Jonas, J., J. Phys. Chem. 100, 16242 (1996).Google Scholar