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Surface Assembled Hybrid Polymers

Published online by Cambridge University Press:  15 February 2011

Philip L. Rose
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
Larry Manziek
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
Michael K. Gallagher
Affiliation:
Rohm and Haas Company, Research Laboratory, 727 Norristown Road, Spring House, PA, 19477
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Abstract

Novel copolymer composite resins have been synthesized using the surface assembled hybrid technology. Monodisperse polystyrene/DVB microspheres with diameters of 5.3 and 7.5 μm and polydisperse carbonaceous and acrylic microspheres with diameters ranging from 5–30 μm have been assembled onto the surface of styrene and acrylonitrile based gel and macroreticular resins.

Carbonaceous adsorbents with holes of controlled diameter on their surfaces have been prepared using the surface assembling technique. Core-shell carbonaceous adsorbents with divergent surface chemistries have been prepared using this technique

Novel catalytic materials have been made and are envisioned using the assembling technique to form short-diffusion path reactive systems. The range of surface functional groups include: strong acid, strong base, palladium, silver, gold and reductive amine-borane.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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