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Supramolecular Chemistry at the Liquid/Solid Interface

Published online by Cambridge University Press:  26 February 2011

Steven De Feyter ,
Hiroshi Uji-i ,
Atsushi Miura ,
Wael Mamdouh ,
Jian Zhang ,
Jan van Esch ,
Ben Feringa ,
A. P. H. J. Schenning ,
E. W. Meijer  and
Frank Wuerthner
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Steven De Feyter
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Celestijnenlaan 200 F, Leuven, N/A, B-3001, Belgium, +32 16 327921, +32 16 327990
Hiroshi Uji-i
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Belgium
Atsushi Miura
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Belgium
Wael Mamdouh
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Belgium
Jian Zhang
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Belgium
Jan van Esch
Affiliation:
[email protected], University of Groningen, Material Science Center, Netherlands
Ben Feringa
Affiliation:
[email protected], University of Groningen, Material Science Center, Netherlands
A. P. H. J. Schenning
Affiliation:
[email protected], Eindhoven University of Technology, Laboratory of Macromolecular and Organic Chemistry, Netherlands
E. W. Meijer
Affiliation:
[email protected], Eindhoven University of Technology, Laboratory of Macromolecular and Organic Chemistry, Netherlands
Frank Wuerthner
Affiliation:
[email protected], Universität Würzburg, Laboratory of Organic and Inorganic Molecular Chemistry, Germany
Frans De Schryver
Affiliation:
[email protected], Katholieke Universiteit Leuven, Chemistry, Belgium
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Abstract

The liquid/solid interface provides an ideal environment to investigate self-assembly phenomena and scanning tunneling microscopy (STM) is the preferred methodology to probe the structure and the properties of physisorbed monolayers on the nanoscale. Physisorbed monolayers are of relevance in areas such as lubrication, patterning of surfaces on the nanoscale, and thin film based organic electronic devices, to name a few. It's important to gain insight in the factors which control the ordering of molecules at the liquid/solid interface in view of the targeted properties. STM provides detailed insight into the importance of molecule-substrate (epitaxy) and molecule-molecule interactions to direct the ordering of both achiral and chiral molecules on the atomically flat surface. The electronic properties of the self-assembled physisorbed molecules can be probed by taking advantage of the operation principle of STM, revealing spatially resolved intramolecular differences within these physisorbed molecules.

Keywords

adsorptionnanostructurescanning probe microscopy (SPM)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 901: Symposium R – Assembly at the Nanoscale – Toward Functional Nanostructured Materials , 2005 , 0901-Ra20-01
Copyright
Copyright © Materials Research Society 2006

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References

1 Liu, G.-Y., Xu, S. and Qian, Y., Acc. Chem. Res. 33, 457 (2000).Google Scholar
2 Maoz, R., Cohen, S. R. and Sagiv, J., Adv. Mat. 11, 55 (1999).Google Scholar
3 Rabe, J. P. and Buchholz, S., (1991) Science 253, 424 (1991).Google Scholar
4 Yokoyama, T., Yokoyama, S., Kamikado, T., Okuno, Y. and Mashiko, S., Nature 413, 619 (2001).Google Scholar
5 Giancarlo, L. C. and Flynn, G. W., Annu. Rev. Phys. Chem. 49, 297 (1998).Google Scholar
6 De Feyter, S., Gesquiére, A., Abdel-Mottaleb, M. M., Grim, P. C. M., De Schryver, F. C., Meiners, C., Sieffert, M., Valiyaveettil, S. and Müllen, K., Acc. Chem. Res. 33, 520 (2000).Google Scholar
7 Subramanian, S. and Zaworotko, M. J., Coord. Chem. Rev. 137, 357 (1994).Google Scholar
8 De Feyter, S. and De Schryver, F. C., Chem.Soc.Rev. 32, 139 (2003).Google Scholar
9 Schuurmans, N., Uji-i, H., Mamdouh, W., De Schryver, F. C., Feringa, B. L., van Esch, J. and De Feyter, S., J. Am. Chem. Soc. 126, 13884 (2004).Google Scholar
10 Gesquiére, A., Jonkheijm, P., Schenning, A. P. H. J., Mena-Osteritz, E., Bäuerle, E. P., Jonkheijm, P., De Feyter, S., De Schryver, F. C. and Meijer, E. W. J., Mater. Chem. 13, 2164 (2003).Google Scholar
11 Gesquiére, A., Jonkheijm, P., Hoeben, F. J. M., Schenning, A. P. H. J., De Feyter, S., De Schryver, F. C. and Meijer, E. W., Nano Lett. 4, 1175 (2004).Google Scholar
12 Jonkheijm, P., Miura, A., Zdanowska, M., Hoeben, F., De Feyter, S., Schenning, A. P. H. J., De Schryver, F. C. and Meijer, E. W., Angew. Chem. Int. Ed. 43, 74 (2004).Google Scholar
13 Miura, A., Jonkheijm, P., De Feyter, S., Schenning, A. P. H. J., Meijer, E. W. and De Schryver, F. C., Small 1, 131 (2005).Google Scholar
14 De Feyter, S., Miura, A., Yao, S., Chen, Z., Würthner, F., Jonkheijm, P., Schenning, A. P. H. J., Meijer, E. W. and De Schryver, F. C., Nano Lett. 5, 77 (2005).Google Scholar
15 Miura, A., Chen, Z., De Feyter, S., Zdanowska, M., H. Uji-i, Jonkheijm, P., Schenning, A. P. H. J., Meijer, E. W., Würther, F. and De Schryver, F. C., J. Am. Chem. Soc. 125, 14968 (2003).Google Scholar
16 Uji-i, H., Miura, A., Schenning, A., Meijer, E. W., Chen, Z., Würthner, F., De Schryver, F. C., der Auweraer, M.Van and De Feyter, S., ChemPhysChem 6, 2389 (2005)Google Scholar