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Study of Onion-Like Carbon (OLC) Formation from Ultra Disperse Diamond (UDD)

Published online by Cambridge University Press:  15 February 2011

Vladimir L. Kuznetsov ,
Andrey L. Chuvilin ,
Yurii V. Butenko ,
Igor Yu. Mal'kov ,
Anton K. Gutakovskii ,
Sergey V. Stankus  and
Raschid A. Khairulin
Vladimir L. Kuznetsov
Affiliation:
Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
Andrey L. Chuvilin
Affiliation:
Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
Yurii V. Butenko
Affiliation:
Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
Igor Yu. Mal'kov
Affiliation:
Lavrentiev Institute of Hydrodynamics, Novosibirsk 630090, Russia
Anton K. Gutakovskii
Affiliation:
Lavrentiev Institute of Hydrodynamics, Novosibirsk 630090, Russia
Sergey V. Stankus
Affiliation:
Institute of Thermophysics, Novosibirsk 630090, Russia
Raschid A. Khairulin
Affiliation:
Institute of Thermophysics, Novosibirsk 630090, Russia
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Abstract

Measurements of diamond bulk density change of carbon powder in the annealing of UDD to OLC (293-2400 K) was performed by irradiating the samples with a narrow beam of gamma quanta (137Cs gamma-ray source). The intermediates of UDD to OLC transformation were registered by high resolution TEM. The annealing products were also characterized by true density and specific area adsorption measurements. The structural rearrangement of UDD begins from the surface towards a crystal bulk. UDD annealing proceeds via particles composed of semi-spherical shells enclosed one-to-one with the rest of diamond core and quasispiral carbon shells. The influence of particle size on the temperature of UDD to OLC transformation was found.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 359: Symposium G – Science and Technology of Fullerene Materials , 1994 , 105
Copyright
Copyright © Materials Research Society 1995

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References

REFERENCES

1. Kroto, H.W., Heath, J.R., O'Brien, S.C., Curl, R.F. and Smalley, R.E., Nature 318, 162 (1985).Google Scholar
2. Kratschmer, W., Lamb, L.D., Fostiropoulos, K. and Huffman, D., Nature 347, 354 (1990).Google Scholar
3. Carbon 30 No 8 (1992), Special issue on fullerenes, Guest editor: Kroto, H..Google Scholar
4. Parker, D.H., Chatterjee, K., Wurz, P., Lykke, K.R., Pellin, M.J., Stock, L.M., and Hemminger, J.C., Carbon 30, No.8, 1167 (1992).Google Scholar
5. Ugarte, D., Nature 359, 707 (1992).Google Scholar
6. Ugarte, D., Chem.Phys.Letters 207, 473 (1993).Google Scholar
7. Harris, P.J.F., European Microscopy and Analysis, Sept. 1994, 13.Google Scholar
8. Heer, W.A. de and Ugarte, D., Chem.Phys.Letters 207, 480 (1993).Google Scholar
9. Kuznetsov, V.L., Mal'kov, I.Yu., Chuvilin, A.L., Moroz, E.M., Kolomiichuk, V.N., Shaichutdinov, Sh. K., and Butenko, Yu. V., Carbon 32, 873 (1994).Google Scholar
10. Mal'kov, I.Yu., Titov, V.M., Kuznetsov, V.L., Chuvilin, A.L., Fizika Gorenia i Vzryva (Russ.) 30, No 1, 130 (1994).Google Scholar
11. Kuznetsov, V.L., Chuvilin, A.L., Butenko, Yu. V., Mal'kov, I.Yu. and Titov, V.M., Chem.Phys.Lett. 222, 343 (1994).Google Scholar
12. Kuznetsov, V.L., Aleksandrov, M.N., Zagoruiko, I.V., Chuvilin, A.L., Moroz, E.M., Kolomiichuk, V.N., Likholobov, V.A., Brylyakov, P.M. and Sacovich, G.V.. Carbon 29, 665 (1991).Google Scholar
13. Stankus, S.V. and Khairulin, R.A., Teplophizica Vysokikh Temperatur (in Russian) 30, 487 (1992)Google Scholar
14. Stankus, S.V. and Khairulin, R.A., Russ. J.Engineering Thermphys. 1, 193 (1991).Google Scholar
15. Genat, M., Margulis, L., Hodes, G., and Tenne, R., Thin Solid Films 217, 91 (1992).Google Scholar
16. Tenne, R., Margulis, L., Genut, M., and Hodes, G., Nature 360, 444 (1992).Google Scholar
17. Moser, J., Liao, H., Levy, F., J.Phys. D. appl. Phys. 23, 624 (1990).Google Scholar
18. Lyamkin, A.I., Petrov, E.A., Ershov, A.P., Sacovich, G.V., Staver, A.M. and Titov, V.M., Dokl.Acad.Nauk SSSR 302, 611 (1988).Google Scholar
19. Mal'kov, I.Yu., Fizika Gorenia i Vsryva 27, No 5, 136 (1991).Google Scholar