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The Study of Deep Levels in CdS/CdTe Solar Cells Using Admittance Spectroscopy and its Modifications

Published online by Cambridge University Press:  01 February 2011

A.S. Gilmore
Affiliation:
Colorado School of Mines, Dept. of Physics, Golden, CO 80401, U.S.A.
V. Kaydanov
Affiliation:
Colorado School of Mines, Dept. of Physics, Golden, CO 80401, U.S.A.
T.R. Ohno
Affiliation:
Colorado School of Mines, Dept. of Physics, Golden, CO 80401, U.S.A.
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Abstract

Measurements of an admittance over a wide frequency range were used to detect the defect electronic states and evaluate their properties in CdTe based solar cells. Cells prepared in various ways, from various facilities all exhibited a high defect state density (>1014cm-3, and often >1015cm-3). Two distinct energy levels or bands were observed at approximately 0.37eV and 0.61eV above the valence band. These were tentatively attributed to CuCd- and VCd-- respectively. Various post-CdTe deposition treatments, as well as stress tests, were applied to alter the defect state densities. The high defect concentration measured was not observed to inhibit cell performance in any way.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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