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Studies of the blue to red phase transition in polydiacetylene nanocomposites and blends

Published online by Cambridge University Press:  31 January 2011

Anitha Patlolla ,
Qi Wang ,
Anatoly Frenkel ,
James L Zunino III ,
Donald R Skelton  and
Zafar Iqbal
Anitha Patlolla
Affiliation:
[email protected], New Jersey Institute of Technology, Chemistry and Environmental sciences, Newark, New Jersey, United States
Qi Wang
Affiliation:
[email protected], Yeshiva university, Physics, Newyork, New York, United States
Anatoly Frenkel
Affiliation:
[email protected], Yeshiva University, Physics, NEWyork, New York, United States
James L Zunino III
Affiliation:
[email protected], U.S.Army ARDEC, Picattinny Arsenal, New Jersey, United States
Donald R Skelton
Affiliation:
[email protected], U.S.Army ARDEC, Picattinny Arsenal, New Jersey, United States
Zafar Iqbal
Affiliation:
[email protected]@njit.edu, New Jersey Institute of Technology, Chemistry and Environmental sciences, Newark, New Jersey, United States
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Abstract

The conjugated polymeric backbone of polydiacetylenes (PDAs), comprising of alternating ene-yne groups, undergo intriguing stress-, chemical- or temperature-induced chromatic phase transitions associated with the disruption of the backbone structure and shortening of the conjugation length. PDAs, such as polymerized 10, 12 pentacosadiynoic acids (PCDA), when incorporated with inorganic oxides form nanocomposites and uniform blends with polymers. Blends of poly-PCDA with polymers, such as polyvinyl alcohol, polyvinylidene fluoride and cellulose increase the blue to red transition temperature without affecting the irreversibility of the red phase. However, the addition of zinc oxide to pure poly-PCDA makes the red phase highly reversible and substantially increases the blue to red transition temperature. The addition of TiO2 to poly-PCDA on the other hand does not affect the irreversibility of the red phase and the chromatic transition temperature. In order to understand the atomic scale interactions associated with these changes in the chromatic transitions, we have investigated both the nanocomposites and polymer blends using Raman and Fourier-transform infrared spectroscopy, and extended X-ray absorption fine structure (EXAFS) measurements

Keywords

compositeblendpolymer
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1190: Symposium NN – Active Polymers , 2009 , 1190-NN11-04
Copyright
Copyright © Materials Research Society 2009

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References

1 Carpick, R. W., Sasaki, D.Y., Marcus, M.S., Eriksson, M.A. and Burns, A.R., J. Physics: Condensed Matter 16, R679 (2004).Google Scholar
2 Lee, S. and Kim, J M., J. Macromolecules 40, 26 (2007).Google Scholar
3 Lu, Y., Yang, Y., Sellinger, A., Lu, M., Huang, J., Fan, H., Hadded, R., Lopez, G., Burns, A.R., Sasaki, D.Y., Shelnutt, J. and Brinker, C.J., Nature 410, 913 (2001).10.1038/35073544Google Scholar
4 Dei, S., Matsumoto, A. and Matsumoto, A., Macromolecules 41, 2467 (2008).10.1021/ma702789fGoogle Scholar
5 Iqbal, Z., Murthy, N.S., Khanna, Y.P., Szobota, J.S., Dalterio, R.A. and Owens, F.J., J. Phys. C: Solid State Phys. 20, 4283 (1987).10.1088/0022-3719/20/27/008Google Scholar
6 Wenzel, M. and Atkinson, G.H., J. Amer. Chem. Soc. 111, 6123 (1989).10.1021/ja00198a020Google Scholar
7 Eckhardt, H., Boudreaux, D.S. and Chance, R.R., J. Chem. Phys 85, 4116 (1986).10.1063/1.450882Google Scholar
8 Gu, Y., Cao, W., Zhu, L., Chen, D., and Jiang, M., Macromolecules 41, 2299 (2008).10.1021/ma800023fGoogle Scholar
9 Ahn, D.J., Chae, E H., Lee, G.S., Shim, H Y., Chang, TE., Ahn, K D., and Kim, J M., J. Amer. Chem. Soc. 125, 8976 (2003).10.1021/ja0299001Google Scholar