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Studies of Substituted R2 T14 B and R2 Co17 Systems (T = Fe or Co)

Published online by Cambridge University Press:  25 February 2011

W. E. Wallace
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
A. T. Pedziwiatr
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
E. B. Boltich
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
H. Kevin Smith
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
S. Y. Jiang
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
S. G. Sankar
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
E. Oswald
Affiliation:
Mellon Institute and Magnetics Technology Center, Carnegie-Mellon University, Pittsburgh, PA 15213
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Abstract

Certain R2Co17 and R2 T14 B systems (R = a rare earth, T = Fe or Co) are of significance for use in the fabrication of high energy magnets. Improvements in these systems as high energy magnet materials are effected by partially replacing Co or T by appropriate d transition metals. A description is given of the magnetic behavior of a number of systems based on R2 Co17 and R2T14 B. Also, an account is given of recent work dealing with the systems RCo4 B and PrCo4-xFex B. The latter materials have large magnetizations and high Curie temperatures. However, they are not useful permanent magnet materials because they exhibit planar anisotropy.

Results of some Auger spectroscopy studies of R2 Fe14 B systems (R = Pr,Nd or Er) are presented. This work shows the intergranular region to be rich in B, O and R. This region is undoubtedly non-magnetic, a feature which is most probably of significance in regard to the observed coercivity of R2 Fe14 B magnets.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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References

REFERENCES

1. Wallace, W. E., Pedziwiatr, A. T., Boltich, E. B., Pourarian, F., Oswald, E. and Jiang, S. Y., Acta Physica Polonica, to appear.Google Scholar
2. Pedziwiatr, A. T., Wallace, W. E. and Burzo, E., IEEE Trans. Mag., accepted.Google Scholar
3. Pedziwiatr, A. T. and Wallace, W. E., submitted.Google Scholar
4. Bozorth, R. M., Ferromagnetism, Van, D. Nostrand Co., Inc. (1951).Google Scholar
5. Burzo, E. and Ursu, I., J. Appl. Phys. 50, 1471 (1979).Google Scholar
6. Burzo, E., J. Phys. F. 10, 2025 (1980).Google Scholar
7. Burzo, E., Lazar, D. P. and Ciorascu, M., Phys. Stat. Solidi B 65(2), K145 (1974).Google Scholar
8. Huang, M. Q., Boltich, E. B., Wallace, W. E. and Oswald, E., J. Mag. Mag. Mat. 60, 270 (1986).Google Scholar
9. Wallace, W. E., Craig, R. S. and Rao, V. U. S., Advances in Chemistry Series, No. 186, “Solid State Chemistry: A Contemporary Overview,” Holt, Smith L., Milstein, Joseph B. and Robbins, Murray, eds. American Chemical Society, 1980, p. 207.Google Scholar
10. Abache, C. and Oesterreicher, H., J. Appl. Phys. 57, 4112 (1985).Google Scholar
11. Schaller, H. J., Craig, R. S. and Wallace, W. E., J. Appl. Phys. 43, 3161 (1972).Google Scholar
12. Ray, A. E. and Strnat, K. J., IEEE Trans. Magn. MAG–8, 516 (1972).Google Scholar
13. Satyanarayana, M. V., Fujii, H. and Wallace, W. E., J. Mag. Mag. Mat. 40, 241 (1984).Google Scholar
14. Fujii, H., Satyanarayana, M. V. and Wallace, W. E., J. Appl. Phys. 2371 (1982).Google Scholar
15. Wallace, W. E. and Narasimhan, K. S. V. L., in The Science and TechnoloRy of Rare Earth Materials, Wallace, W. E. and Subbarao, E. C., eds. Academic Press, Inc., New York (1980), p. 329.Google Scholar
16. Ojima, T., Tomizawa, S., Yoneyama, T. and Hori, T., IEEE Trans. Mag. MAG–13, 1317 (1977).Google Scholar
17. Fujii, H., Satyanarayana, M. V. and Wallace, W. E., Solid State Commun. 41, 443 (1982).Google Scholar
18. Oswald, E., Ph. D. Thesis, University of Pittsburgh, 1986.Google Scholar
19. Spada, F., Abache, C. and Oesterreicher, H., J. Less-Common Met. 99 L21 (1984).Google Scholar
20. Pedziwiatr, A. T., Jiang, S. Y., Wallace, W. E., Burzo, E. and Pop, V., J. Mag. Mag. Mat., to appear.Google Scholar
21. Smith, H. K. and Wallace, W. E., Lanthanides and Actinides, 1, 217 (1985).Google Scholar
22. Elbicki, Janean M. and Wallace, W. E., to be published.Google Scholar