Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-29T08:16:14.460Z Has data issue: false hasContentIssue false

The Structure of a-Si:H,F/a-Si,Ge:H,F Interfaces*)

Published online by Cambridge University Press:  26 February 2011

J. P. Conde
Affiliation:
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
D.-S. Shen
Affiliation:
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
I. H. Campbell
Affiliation:
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
P. M. Fauchet
Affiliation:
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
S. Wagner
Affiliation:
Department of Electrical Engineering, Princeton University, Princeton, New Jersey 08544
Get access

Abstract

We study the interface between un-alloyed a-Si:H,F and an a-Si0.4,Ge0.6:H,F alloy using superlattice structures. From infrared spectroscopy we estimate a width of 8 A for the excess hydrogen layer, and X-ray diffraction data give us a width of 2Å contributing to the width of the diffraction peak. Vibrational Raman scattering data show that the ratios of the number of Si-Si, Ge-Ge and Si-Ge bonds is not altered by changing the number of interfaces. This fact allows us to establish an upper limit for the interface width of 3 atomic layers, i.e. one layer in each partner plus an intermediate layer.

Type
Articles
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

*)

Work supported by the Electric Power Research Institute

References

REFERENCES

[1] Persans, P.D., Ruppert, A.F., Abeles, B., and Tiedje, T., Phys. Rev. B 32, 5558 (1985)CrossRefGoogle Scholar
[2] Abeles, B., Yang, L., Persans, P.D., Stasiewsky, H.S. and Lanford, W., Appl. Phys. Lett. 48, 168 (1986)CrossRefGoogle Scholar
[3] Kolodzey, J., Okada, Y., Shen, D.-S., Chou, S.-F., Schwartz, R. and Wagner, S., “X-Ray Diffraction and Infrared Absorption of Annealed a-SkFLF/a-Si:H,F/a-Si1-x,Gex:H,F Supperlattices”, presented at the Metallurgical Society Meeting on Semiconductor-based Heterostructures, May 1–2, 1986, Murray Hill, NJ, to be published.Google Scholar
[4] Kolodzey, J., Aljishi, S., Schwarz, R. and Wagner, S., “Properties of a-Si,Ge:H,F Alloys Prepared by RF Glow Discharge in and UHV Reactor”, J. Vac. Sci. Tech. A, November/December 1986 CrossRefGoogle Scholar
[5] Kolodzey, J., Aljishi, S., Schwarz, R., Shen, D.-S., Quinlan, S., Lyon, S.A. and Wagner, S., MRS Symposia Proceedings, 70, 429 CrossRefGoogle Scholar
[6] Lucovsky, G., Galeener, F.L., Keezer, R.C., Geils, R.H. and Six, H.A., Phys. Rev. B 10, 5134 (1974)CrossRefGoogle Scholar
[7] Shen, D.-S., Kolodzey, J., Slobodin, D., Conde, J.P., Lane, C., Campbell, I.H., Fauchet, P.M. and Wagner, S., MRS Symposia Proceedings, 70, 301Google Scholar
[8] Fang, C.J., Gruntz, K.J., Ley, L. and Cardona, M., J. Non-Cryst. Solids, 35 & 36, 255 (1980)CrossRefGoogle Scholar
[9] Antoine, A.M. and Drevillon, B., “A Spectrocopic Ellipsometric Study Of a-Ge:H/a-Si:H Interfaces”,to be publishedGoogle Scholar
[10] Phillips, J.C., “Bonds and Bands in Semiconductors”, Academic Press, New York, 1973, p. 22 Google Scholar