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Structural Aspects of the Polyaniline Family of Electronic Polymers

Published online by Cambridge University Press:  25 February 2011

J. P. Pouget ,
M. Laridjani ,
M. E. Jozefowicz ,
A. J. Epstein ,
E. M. Scherr  and
A. C. MacDiarmid
J. P. Pouget
Affiliation:
Laboratoire de Physique des Solides CURA 02 CNRS) Université de Paris Sud, 91405 Orsay, (France).
M. Laridjani
Affiliation:
Laboratoire de Physique des Solides CURA 02 CNRS) Université de Paris Sud, 91405 Orsay, (France).
M. E. Jozefowicz
Affiliation:
Department of Physics and Department of Chemistry, The Ohio State University, Columbus, Ohio 43210, (U.S.A.).
A. J. Epstein
Affiliation:
Department of Physics and Department of Chemistry, The Ohio State University, Columbus, Ohio 43210, (U.S.A.).
E. M. Scherr
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104, (U.S.A.).
A. C. MacDiarmid
Affiliation:
Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104, (U.S.A.).
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Abstract

Recent structural studies of the polyaniline family of electronic polymers in the base and salt forms are reviewed. We describe the crystalline and amorphous structures of the two classes of emeraldine. The structural evolution with HC1 doping and ring substitutions are also discussed in relationship with the electronic properties of these materials. Implications for charge transport phenomena are also considered.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 589
Copyright
Copyright © Materials Research Society 1992

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References

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