Hostname: page-component-78c5997874-dh8gc Total loading time: 0 Render date: 2024-11-05T09:08:59.599Z Has data issue: false hasContentIssue false
  • English
  • Français

Structural and Physical Property Trends of the Hyperstoichiometric Series, La2Ni(1-x)CoxO4+δ

Published online by Cambridge University Press:  11 February 2011

G. Amow ,
P. S. Whitfield ,
J. Davidson ,
R. P. Hammond ,
C. Munnings  and
S. Skinner
G. Amow
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada.
P. S. Whitfield
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada.
J. Davidson
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada.
R. P. Hammond
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada. Neutron Program tor Materials Research, Chalk River Laboratories, Chalk River, Ontario, Canada.
C. Munnings
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada. Neutron Program tor Materials Research, Chalk River Laboratories, Chalk River, Ontario, Canada. Centre for Ion Conducting Membranes, Department of Materials, Imperial College London, London, UK.
S. Skinner
Affiliation:
Institute for Chemical Process and Environmental Technology, National Research Council, Ottawa, Ontano, Canada. Neutron Program tor Materials Research, Chalk River Laboratories, Chalk River, Ontario, Canada. Centre for Ion Conducting Membranes, Department of Materials, Imperial College London, London, UK.
Get access

Abstract

Members of the Ruddlesden-Popper system, La2Ni(1-x)CoxO4+δ (0.00 ≤ × ≤ 1.00), were synthesized and studied for their potential use as cathodes for solid-oxide fuel cells. An unusual structural trend has been noted across the series, which appears to correlate with the oxygen-hyperstoichiometry observed. Details of the structural variance by x-ray and neutron diffraction, as well as selected physical properties for this system will be presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD8.10
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Skinner, S.J. and Kilner, J.A., Solid State Ionics, 135, 709–712, 2000 Google Scholar
Shaw, C.K.M., Kilner, J.A., 4th European SOFC Forum Proceedings, Lucerne, Switzerland, eds. McEvoy, A.J., July 2000 Google Scholar
Vashook, V.V., Ullmann, H., Olshevskaya, O.P., Kulik, V.P., Lukashevich, V.E., and Kokhanovskij, L.V., Solid State Ionics, 13891), 99, 2001.Google Scholar
4). Rice, D.E. and Buttrey, D.J., J. Solid State Chem., 105, 197–210, 1993 Google Scholar
5). Jorgensen, J.D., Dabrowski, B., Pei, S., Richards, D.R. and Hinks, D.G., Phys. Rev. B., 40(4), 2187–2199 Google Scholar
6). Ganguly, P. and Rao, C.N.R., Mater. Res. Bull., 8, 405, 1973 Google Scholar
7). Bassat, J.M., Odier, P. and Loup, J.P., J. Solid State Chem., 110, 124–135, 1994 Google Scholar
8). Nishiyama, S., Sakaguchi, D. and Hattori, T., Solid State Communications, 94(4), 279–282, 1995.Google Scholar
9). Larson, A.C. and Von Dreele, R.B., “General Structure Analysis System (GSAS)“, Los Alamos National Laboratory Report LAUR 86–748 (1994).Google Scholar
10). Longo, J.M. and Raccah, P.M., J. Solid State Chem., 6, 526, 1973.Google Scholar
11). Shannon, R.D. and Prewitt, C.T., Acta Cryst, B25, 925–945, 1969.Google Scholar
12). Goodenough, J.B. and Ramasesha, S., Mater. Res. Bull., 17, 383–90, 1982.Google Scholar
13). Millburn, J.E., Green, M.A., Neumann, D.A. and Rosseinsky, M.J., J. Solid State Chem., 145, 401–420, 1999 Google Scholar