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Stratification of Fullerenes

Published online by Cambridge University Press:  22 February 2011

K. Levon ,
D. Weng ,
J. Mao  and
H.K. Lee
K. Levon
Affiliation:
Department of Chemistry, Polytechnic University, 6 Metrotech Center, Brooklyn, NY 11201, and J.M. TOUR, W.A. SCHRIVENS, Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208
D. Weng
Affiliation:
Department of Chemistry, Polytechnic University, 6 Metrotech Center, Brooklyn, NY 11201, and J.M. TOUR, W.A. SCHRIVENS, Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208
J. Mao
Affiliation:
Department of Chemistry, Polytechnic University, 6 Metrotech Center, Brooklyn, NY 11201, and J.M. TOUR, W.A. SCHRIVENS, Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208
H.K. Lee
Affiliation:
Department of Chemistry, Polytechnic University, 6 Metrotech Center, Brooklyn, NY 11201, and J.M. TOUR, W.A. SCHRIVENS, Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208
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Abstract

Dodecylated C60 {(Do)nC60(H)n} and butylated C60 {(Bu)nC60(H)n} were synthesized. Spectroscopic and thermal methods, mass spectrometry, XPD, have been employed to characterize the products. X-ray Powder Diffraction (XPD) results reveal that the facecentered- cubic (fcc) structure of C60 expands to a primitive hexagonal structure upon butylation and to a layered structure upon dodecylation. Butylated C60 diffraction pattern has been indexed as a primitive hexagonal structure with ao = 11.5 angstroms and axial ratio = 1.169. The dodecylated C60 also shows sidechain melting behavior with a transition temperature of around 25°C. The paraffinic crystals are produced by the interdigitation of the sidechains. Butylated C60 does not show any sidechain melting.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 349: Symposium T – Novel Forms of Carbon II , 1994 , 127
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Wudl, F., “The Chemical Properties of Buckminsterfullerene(C60) and the Birth and Infancy of Fulleroids”, Acc. Chem. Res. 25, 157(1992)Google Scholar
2. Chiang, L.Y., Upasani, R.B., Swirczewski, J.W., “Versatile Nitronium Chemistry for C60 Fullerene Functionalization”, J. Am. Chem, Soc., 114, 10154(1992)Google Scholar
3. Chiang, L.Y., Upasani, R.B., Swirczewski, J.W., Soled, S., “Evidence of Hemiketals Incorporated in the Structure of Fullerols Derived from Aqueous Acid Chemistry”, J. Am. Chem. Soc., 115,5453(1993)Google Scholar
4. Haddon, R.C., “Chemistry of the fullerenes: The Manifestation of Strain in a Class of Continuous Aromatic Molecules”, Science, 261, 1545(1993)Google Scholar
5. Weng, D., Levon, K., “Copolymers of C60 with Acrylics”, unpublished resultsGoogle Scholar
6. Loy, D.A., Assink, R.A., “Synthesis of a C60-p-Xylyene Copolymer”, J. Am. Chem. Soc., 114, 3977(1992)Google Scholar
7. Patil, A.O., Schriver, G.W., Carstensen, B., Lundberg, R.D., “Fullerene functionalized Polymers”, Polymer Bulletin 30, 187(1993)Google Scholar
8. Samulski, E.T., deSimone, J.M., Hunt, M.O. jr, Menceloglu, Y., Jamagin, R.C., York, G.A., Labat, K.B., Wang, H., Chem. Mater., 4, 1153, (1992)Google Scholar
9. Morton, J.R., Preston, F., Krusic, P.J., Hill, S.A., Wasserman, E., “The Dimerization of RC60 Radicals”, J. Am. Chem. Soc., 114, 5454(1992)Google Scholar
10. Sivaraman, N., Dhamodaran, R., Kaliappan, I., “Solubility of C60 in Organic Solvents”, I. Org. Chem., 57, 6077(1992)Google Scholar
11. Morita, S., Zakhidov, A.A., Kawai, T., Araki, H., Yoshino, K., “Electrical Conductivity and ESR Spectrum of Buckminsterfullerene-Doped Poly(3-alkylthiophene)”, Jpn. I. Appl. Phys., 31, L890(1992)Google Scholar
12. Yoshino, K., Morita, S., Uchida, M., Muro, K., Kawai, T., Ohmori, Y., “Novel Electrical and Optical Properties of Poly(3-alkylthiophene) as function of alkyl chain length and their functional applications”, Synthetic Metals, 55–57, 28(1993)Google Scholar
13. Chen, K., Caldwell, W.B., Mirkin, C.A., “Fullerene Self-Assembly onto (MeO)3Si(CH2)3NH2-Modified Oxide Surfaces”, J. Am. Chem. Soc., 115, 1193(1993)Google Scholar
14. Chupa, J.A., Xu, S., Fischetti, R.F., Strongin, R.M., McCauley, J.P. jr., Smith, A.B. III., Blasie, J.K., J. Am. Chem. Soc.,115, 4383(1993)Google Scholar
15. Cox, D.M., Sherwood, R.D., Tindall, P., Greegan, K.M., Anderson, W., Martella, D.J., “Mass Spectrometric, Thermal, and Separation Studies of Fullerenes”, Ch.8, Fullerenes-Synthesis, Properties. and Chemistry of Large Carbon Clusters, ed. by Hammond, G.S. and Kuck, V.J., ACS symposium Series 481, 1992 Google Scholar
16. Heiney, P.A., Fischer, J.E., McGhie, A.R., Romanow, W.J., Denenstein, A.M., McGauleyjr, J.P.., Smith, A.B. III, Cox, D.E., “Orientational Ordering Transition in Solid C60 ”, Phys. Rev. Letters, 66(22), 2911(1991)Google Scholar
17. Hirsch, A., Li, Q., Wudl, F., “Globe-trotting Hydrogens on the Surface of the Fullerene Compound C60H6(N(CH2CH2)2O)6 “, Angew. Chem. Int. Ed. Engl., 30(10), 1309(1991)Google Scholar
18. Wudl, F., Hirsch, A., Khemani, K.C., Suzuki, T., Allemand, P.-M., Koch, A., Eckert, H., Srdanov, G., Webb, H.M., “Survey of Chemical Reactivity of C60, Electrophile and Dienopolarophile Par Excellence”, Ch. 11, Fullerences-Synthesis, Properties, and Chemistry of Large Carbon Clusters, ed. by Hammond, G.S., Kuck, V.J., ACS Symposium Series 481,1992 Google Scholar
19. Saunders, M., Anet, F.A., Nature, 367, 256(1994)Google Scholar
20. Levon, K., Kwei, T.K., Chu, E., Weng, D., unpublished resultsGoogle Scholar
21. Hull, A.W., Davey, W.P., Phys. Rev., 17, 549(1921)Google Scholar
22. Davey, W.P., A Study of Crystal Structure & its Applications, McGraw-Hill Book Co., New York, Pages 596–Google Scholar
23. Hawkins, J.M., Meyer, A., Lewis, T.A., Loren, S, “Crystal Structure of Osmylated C60 ”, Ch.6, Fullerences-Synthesis, Properties, and Chemistry of Large Carbon Clusters, ed. by Hammond, G.S. and Kuck, V.J., ACS Symposium Series 481, 1992 Google Scholar