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Stoichiometry and Alloying Effects on the Phase Stability and Mechanical Properties of TiCr2-Base Laves Phase Alloys

Published online by Cambridge University Press:  22 February 2011

Katherine C. Chen
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
Samuel M. Allen
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
James D. Livingston
Affiliation:
Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

Ti-Cr alloys near the TiCr2 composition have been studied to determine the single-phase Laves field and the associated defects accompanying off-stoichiometry. A combination of metallography, x-ray diffraction, lattice parameter measurements, density measurements and electron microprobe analysis have been used to establish a narrow single-phase region extending towards Ti-rich compositions. All three Laves crystal structures (C14, C36 and C15) were found to exist at different temperatures. Hardness and fracture toughness values determined by Vickers microindentation were studied as a function of alloy composition. Effects of adding Fe, Nb, Mo, and V to TiCr2 on lattice parameter, crystal structure, hardness and fracture toughness are reported.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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References

1. Livingston, J.D., phys. stat. sol. (a) 131, 415 (1992).Google Scholar
2. Livingston, J.D. and Hall, E.L., J. Mater. Res. 5, 5 (1990).Google Scholar
3. Chu, F. and Pope, D.P., Mat. Sci. Eng. A170, 39 (1993); MRS Proc. 288, (1992).Google Scholar
4. Liu, Y., Allen, S.M., and Livingston, J.D., Metall. Trans. 23A, 3303 (1992).Google Scholar
5. Liu, Y., Allen, S.M., and Livingston, J.D., submitted to Metall. Trans.Google Scholar
6. Chen, K.C., Allen, S.M., and Livingston, J.D., Mater. Res. Soc. Proc. 288, 373 (1992).Google Scholar
7. Livingston, J.D., Mater. Res. Soc. Proc. 332, 395 (1994).Google Scholar
8. Murray, J.L., Bull Alloy Phase Diagr. 2 (2), 174 (1981).Google Scholar
9. Evans, A.G. and Charles, E.A., J. Am. Ceram. Soc. 59, 371 (1976).Google Scholar
10. Cook, R.F. and Pharr, G.M., J. Am. Ceram. Soc. 73 (4), 787 (1990).Google Scholar
11. Anstis, G.R., Chantikul, P., Lawn, B.R., and Marshall, D.B., J. Am. Cer. Soc. 64, 533 (1981).Google Scholar
12. Fleischer, R.L. and Zabala, R.J., Metall. Trans. 21A, 1951 (1990).Google Scholar
13. Thoma, D.J. and Perepezko, J.H., Mater. Sci. Eng. A156, 97 (1992).Google Scholar
14. Westbrook, J.H., Mechanical Properties of Intermetallic Compounds, edited by Westbrook, J. H. (John Wiley & Sons, Inc., New York, 1960). p. 26.Google Scholar
15. Paufler, P., Eichler, K. and Schulze, G.E.R., Monatsberichte 12, 949 (1970); P. Paufler, Chemische Gesellschaft 9, 175 (1984).Google Scholar
16. Berry, R.L. and Raynor, G.V., Acta Cryst. 6, 178 (1953).Google Scholar
17. Pearson, W.B., Acta Cryst. B37, 1174 (1981).Google Scholar
18. Van Tyne, R.J., Kessler, H.D., and Hansen, M., Trans. ATME 197, 1209 (1953).Google Scholar
19. Kornilov, I.I., Shakhova, K.I., Budberg, P.B. and Nedumov, N.A., Doklady Akademi Nauk SSSR 149 (6), 1340 (1963).Google Scholar
20. Fleischer, R.L., Scripa Met. et Mater. 27, 799 (1992).Google Scholar