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Statistically Designed Lead Corrosion Experiments for Nuclear Waste Disposal

Published online by Cambridge University Press:  28 February 2011

P. Mani Mathew
Affiliation:
AECL Research, Whiteshell Laboratories, Pinawa, Manitoba, Canada ROE 1LO
P.A. Krueger
Affiliation:
AECL Research, Whiteshell Laboratories, Pinawa, Manitoba, Canada ROE 1LO
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Abstract

This paper describes galvanic corrosion studies of lead, a candidate matrix metal, coupled vith ASTM Grade-2 titanium, a candidate container-shell material, to determine the barrier-lifetime for a lead matrix container - one container concept considered in the Canadian Nuclear Fuel Waste Management Program. In these studies the fractional factorial statistical design of Box-Behnken was used to develop mathematical relationships between the independent variables and the corrosion rate of lead.

Using the mathematical expressions derived in this study, the additional barrier-lifetime that a 25-mm-thick lead layer could provide to a titanium container, which eventually perforates by corrosion, was calculated to be at least 3500 years.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

REFERENCES

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