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Spin, Orbital and Lattice Coupling in the Double Perovskite Ba2154SmMoO6

Published online by Cambridge University Press:  01 February 2011

Abbie Mclaughlin
Abbie Mclaughlin*
Affiliation:
[email protected], University of Aberdeen, Chemistry, Aberdeen, United Kingdom
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Abstract

An unexpectedly high antiferromagnetic transition temperature (TN = 130 K) has been observed in the double perovskite Ba2154SmMoO6 as a result of a strong interplay between spin, orbital and lattice degrees of freedom. A variable temperature neutron diffraction study of Ba2154SmMoO6 demonstrates that the orbital order below TN is as a result of a Jahn-Teller distortion of the MoO6 octahedra.

Keywords

magnetic propertiesstructuralMo
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1148: Symposium PP – Solid-State Chemistry of Inorganic Materials VII , 2008 , 1148-PP04-02
Copyright
Copyright © Materials Research Society 2009

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References

REFERENCES

1. Rao, C. N. R. and Raveau, B., (Eds.) Colossal Magnetoresistance, Charge Ordering and Related Properties of Manganese Oxides (World Scientific, Singapore, 1998).Google Scholar
2. Erickson, A. S., Misra, S., Miller, G. J., Gupta, R. R., Schlesinger, Z., Harrison, W. A., Kim, J. M. and Fisher, I. R., Phys. Rev. Lett. 99, 016404 (2007).Google Scholar
3. Mclaughlin, A. C., Solid State Commun. 137, 354 (2006).Google Scholar
4. Brandle, C. D. and Steinfink, H., Inorg. Chem. 5, 22 (1971).Google Scholar
5. Cussen, E. J., Lynham, D. R. and Rogers, J., Chem. Mater. 18, 2866 (2006).Google Scholar
6. Mclaughlin, A. C. (manuscript in preparation).Google Scholar
7. Mclaughlin, A. C., Phys. Rev. B 78, 132404 (2008).Google Scholar
8. Clarke, S. J., Fowkes, A. J., Harrison, A., Ibbersonand, R. M., Rosseinsky, M. J., Chem. Mater. 10, 372 (1998).Google Scholar