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Spectroscopic Studies of Fast Ionic Conducting Halogenoborate Glasses

Published online by Cambridge University Press:  21 February 2011

M. Massot ,
E. Haro ,
M. Oueslati  and
M. Balkanski
M. Massot
Affiliation:
Laboratoire de Physique des Solides de l'Université P. et M. Curie 4 Place Jussieu, 75252 Paris Cedex 05, France
E. Haro
Affiliation:
Laboratoire de Physique des Solides de l'Université P. et M. Curie 4 Place Jussieu, 75252 Paris Cedex 05, France
M. Oueslati
Affiliation:
Laboratoire de Physique des Solides de l'Université P. et M. Curie 4 Place Jussieu, 75252 Paris Cedex 05, France
M. Balkanski
Affiliation:
Laboratoire de Physique des Solides de l'Université P. et M. Curie 4 Place Jussieu, 75252 Paris Cedex 05, France
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Abstract

Lithium borate glasses B2O3-Li2O-LinX with n=l, X=F, Cl or I are fast ionic conductors. In the perspective of their use as an electrolyte in solid state micro-batteries, spectroscopic investigations of their structure were performed by using experimental techniques sensitive to the local ordering as Raman scattering and F.T.I.R. spectroscopy. In the light of these results, we find that binary and ternary systems (“doped glasses”) with same O/B ratio do not exhibit identical boron-oxygen network. The observed modifications are attributed to interactions between the network and the anions of the doping salt. In addition, the type of the anion plays an important role in the observed effects. We propose here a possible interpretation for the variation of conductivity reported on halide glasses.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 207
Copyright
Copyright © Materials Research Society 1989

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References

1. Levasseur, A., Brethous, J.C., Réau, J.M. and Hagenmuller, P. and Couzi, M., Solid State Ionics 1, 177 (1980).Google Scholar
2. Krogh-Moe, J., Phys. Chem. Glasses 6, 46 (1966).Google Scholar
3. Mozzi, A.L. and Warren, B.B., J. Appl. Cryst. 3, 251 (1970).Google Scholar
4. Bray, P.J., Feller, S.A., Jellison, G.E. Jr and Yun, Y.H., J. of Non Cryst. Solids 38/39, 98 (1980).Google Scholar
5. Bray, P.J., Geissberger, A.E., Bucholtz, F. and Harris, I.A., J. of Non Cryst. Solids 52, 45 (1982).Google Scholar
6. Irion, M. and Couzi, M. and Levasseur, A., Réau, J.M. and Brethous, J.C., J. of Solid St. Chem. 31, 285 (1980).Google Scholar
7. Button, D.P., Tandon, R., King, C., Velez, M.H., Tuller, H.L. and Uhlmann, D.R., J. of Non Cryst. Solids 49, 129 (1982).Google Scholar
8. Levasseur, A., Cales, B., Réau, J.M. and Hagenmuller, P., Mat. Res. Bull. 13, 205 (1978).Google Scholar
9. Goubeau, J. and Keller, H., Z. Anorg. Chem. 272, 303 (1953).Google Scholar
10. Risen, W.M. Jr, J. of Noncryst. Solids 76, 97 (1985).CrossRefGoogle Scholar
11. Galeener, F.L., Barrio, R.A., Martinez, E. and Elliot, R.J., Phys. Rev. Lett. 53, 2429 (1984).Google Scholar
12. Brill, T.W., Philips Research Reports suppl. 2, (1976).Google Scholar
13. Konijnendik, W.L. and Stevel, J.M., J. of Non Cryst. Solids 18, 307 (1975).Google Scholar
14. Massot, M., Julien, C. and Balkanski, M., accepted for publication in infrared Physics.Google Scholar
15. Uchida, N., Maekawa, T. and Yokohawa, T., J. of Non Cryst. Solids 85, 290 (1986).CrossRefGoogle Scholar
16. Borell, N.F. and Su, Goug Jen, Phys. Chem. Glasses 4, 206 (1963).Google Scholar
17. Button, D.P., thesis, P.H.D., B.S. Cornell University (1978).Google Scholar
18. Massot, M., Haro, E., Darwich, R. and Balkanski, M., presented at the International Conference on Raman Spectroscopy, London (1988).Google Scholar
19. Massot, M., Ayyadi, A. and Balkanski, M., Proceeding of the Advanced Study Institute: Science and Technology of Fast Ionic Conductors, Erice, Italy (1987).Google Scholar
20. Massot, M., Julien, C. and Balkanski, M., presented at the Conference of the European Physical Society, Budapest, Hungary (1988).Google Scholar
21. Balkanski, M., Ayyadi, A., Cadet, P., Jouanne, M., Julien, C., Massot, M., Scagliotti, M. and Levasseur, A., Solid State. Commun. 57 41 (1986).Google Scholar