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Spectroscopic Ellipsometry Study of rf-Sputtered a-Ge Films

Published online by Cambridge University Press:  21 February 2011

J. R. Blanco
Affiliation:
On leave of absence from Hughes Aircraft Company, EL Sequndo, CA 09245
R. Messier
Affiliation:
The Pennsylvania State University, Materials Research Laboratory, University Park, PA 16802
K. Vedam
Affiliation:
Also with the Department of Physics, The Pennsylvania State University, University Park, PA 16802
P. J. McMarr
Affiliation:
The Pennsylvania State University, Materials Research Laboratory, University Park, PA 16802
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Abstract

Sputtered amorphous germanium films have been examined by spectroscopic ellipsometry. a technique known to yield the void fraction in the bulk of the film,. (and hence a measure of density, ρcalc) with a high degree of precision, Considering the commonly accepted values of the dielectric function and the directly measured density, ρexpt, of Paul, Connell and Tomkin (1973), as the reference data, we reportf that ρcalc for some a-Ge films can be greater than that of crystalline Ge. Examination of the top surface of the sputter deposited films indicates that the highest densities are achieved under conditions of high energy ion bombardment of the film. This study indicates that a more detailed microscopic model of the structure of a-Ge must be considered.

Type
Research Article
Copyright
Copyright © Materials Research Society 1985

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