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Solvate Ionic Liquids and Their Application to Lithium Batteries: Glyme-Lithium Bis(fluorosulfonyl)amide Equimolar Complexes

Published online by Cambridge University Press:  25 October 2012

Kazuki Yoshida ,
Mizuho Tsuchiya ,
Naoki Tachikawa ,
Kaoru Dokko  and
Masayoshi Watanabe
Kazuki Yoshida
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Mizuho Tsuchiya
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Naoki Tachikawa
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Kaoru Dokko
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Masayoshi Watanabe
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
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Abstract

The physicochemical properties of glyme-Li[FSA] (FSA: bis(fluorosulfonyl)amide) equimolar complexes were investigated. The self-diffusion coefficients of glymes and Li+ as determined by pulsed-field gradient spin-echo nuclear magnetic resonance spectroscopy in equimolar complexes were almost identical, suggesting that all of the glyme molecules coordinated with Li+. Electrochemical characterization revealed that the oxidative stability of glyme molecules was enhanced by complexing with Li+. Using [Li(glyme)1][FSA] electrolytes and a LiFePO4cathode, a lithium secondary battery could be stably operated for more than 100 cycles at room temperature.

Keywords

energy storageenergetic materialionic conductor
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1473: Symposium BBB – Functional Materials and Ionic Liquids , 2012 , mrss12-1473-bbb02-03
Copyright
Copyright © Materials Research Society 2012

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References

REFERENCES

Armand, M. and Tarascon, J.-M., Nature, 451, 652 (2008).10.1038/451652aCrossRefGoogle Scholar
Garcia, B., Lavallée, S., Perron, G., Michot, C., and Armand, M., Electrochim. Acta, 49, 4583 (2004).10.1016/j.electacta.2004.04.041CrossRefGoogle Scholar
Tachikawa, N., Park, J.-W., Yoshida, K., Tamura, T., Dokko, K., and Watanabe, M., Electrochemistry, 5, 349 (2010).10.5796/electrochemistry.78.349CrossRefGoogle Scholar
Shobukawa, H., Tokuda, H., Tabata, S., and Watanabe, M., Electrochim. Acta, 50, 304 (2004).10.1016/j.electacta.2004.01.096CrossRefGoogle Scholar
Shobukawa, H., Tokuda, H., Susan, M.A.B.H., and Watanabe, M., Electrochim. Acta, 50, 3872 (2005).10.1016/j.electacta.2005.02.043CrossRefGoogle Scholar
Yoshida, K., Nakamura, M., Kazue, Y., Tachikawa, N., Tsuzuki, S., Seki, S., Dokko, K., and Watanabe, M, J. Am. Chem. Soc., 133, 13121 (2011).10.1021/ja203983rCrossRefGoogle Scholar
Tamura, T., Hachida, T., Yoshida, K., Tachikawa, N., Dokko, K., and Watanabe, M., J. Power Sources, 195, 6095 (2010).10.1016/j.jpowsour.2009.11.061CrossRefGoogle Scholar
Tamura, T., Yoshida, K., Hachida, T., Tsuchiya, M., Nakamura, M., Kazue, Y., Tachikawa, N., Dokko, K., and Watanabe, M., Chem. Lett., 39, 753 (2010).10.1246/cl.2010.753CrossRefGoogle Scholar
Yoshida, K., Tsuchiya, M., Tachikawa, N., Dokko, K., and Watanabe, M., J. Phys. Chem. C, 115, 18384 (2011).10.1021/jp206881tCrossRefGoogle Scholar
Angell, C.A., Ansari, Y., Zhao, Z.F., Faraday Discuss., 154, 9 (2011).10.1039/C1FD00112DCrossRefGoogle Scholar
Matsumoto, H., Sakaebe, H., Tatsumi, K., Kikuta, M., Ishiko, E., and Kono, M., J. Power Sources, 160, 1308 (2006).10.1016/j.jpowsour.2006.02.018CrossRefGoogle Scholar
Ishikawa, M., Sugimoto, T., Kikuta, M., Ishiko, E., and Kono, M., Journal of Power Sources, 162, 658 (2006).10.1016/j.jpowsour.2006.02.077CrossRefGoogle Scholar
Tokuda, H., Tsuzuki, S., Susan, M.A.B.H., Hayamizu, K., and Watanabe, M., J. Phys. Chem. B, 110, 19593 (2006).10.1021/jp064159vCrossRefGoogle Scholar