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Solid Phase Crystallization of LPCVD Amorphous Si Films by Nucleation Interface Control

Published online by Cambridge University Press:  03 September 2012

Eui-Hoon Hwang
Affiliation:
Department of Metallurgy and Materials Science, Hong-Ik University Seoul, 121-791, Korea.
Jae-Sang Ro
Affiliation:
Department of Metallurgy and Materials Science, Hong-Ik University Seoul, 121-791, Korea.
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Abstract

A novel method for the fabrication of poly-Si films with a large grain size is reported using solid phase crystallization (SPC) of LPCVD amorphous Si films by nucleation interface control. The reference films used in this study were 1000 Ǻ -thick a-Si films deposited at 500°C at a total pressure of 0.35 Torr using Si2H6/He. Since the deposition condition changes the incubation time, i.e. nucleation rate, and since nucleation occurs dominantly at a-Si/SiO2 interface, we devised the following deposition techniques for the first time in order to obtain the larger gain size. A very thin a-Si layer (~ 50 Ǻ) with the deposition conditions having long incubation time is grown first and then the reference films (~ 950 Ǻ) are grown successively. Various composite films with different combinations were tested. The crystallization kinetics of composite films was observed to be determined by the deposition conditions of a thin a-Si layer at the a-Si/SiO2 interface. Nucleation interface was also observed to be modified by interrupted gas supply resulting in the enhancement of the grain size.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

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