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SOL-GEL DERIVED SENSOR MATERIALS FOR USE IN AQUEOUS TRANSITION METAL ION DETECTION

Published online by Cambridge University Press:  25 February 2011

L. M. Yates III ,
D. Arbuthnot ,
H.J. Harmon  and
E. T. Knobbe
L. M. Yates III
Affiliation:
Department of Chemistry and University Center for Laser ResearchOklahoma State University, Stillwater, Oklahoma 74078-0447
D. Arbuthnot
Affiliation:
Department of Chemistry and University Center for Laser ResearchOklahoma State University, Stillwater, Oklahoma 74078-0447
H.J. Harmon
Affiliation:
Department of MicrobiologyOklahoma State University, Stillwater, Oklahoma 74078-0447
E. T. Knobbe
Affiliation:
Department of Chemistry and University Center for Laser ResearchOklahoma State University, Stillwater, Oklahoma 74078-0447
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Abstract

Opto-chemical transducers, which exhibit changes in luminescence and/or absorption characteristics as a function of local conditions, are currently of great interest for use in performing quantitative chemical analyses. Present research is focused on the preparation and characterization of novel optrode materials which may be remotely interrogated via optical fiber carriers. The approach under investigation involves preparation of sol-gel derived films which are sensitized by the entrapment of analyte-complexing organic probe molecules. Zn(II)aq induced perturbations to the luminescence behavior of a porphyrin derivative entrapped within a porous sol-gel derived host matrix are detailed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 286: Symposium J – Nanophase and Nanocomposite Materials , 1992 , 265
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

1. Zhu, C., Hieftje, G.M., Anal. Chem., 62, 2079 (1990)Google Scholar
2. Marling, J.B., Gregg, D.W., Thomas, S.J., IEEE J. Quant Elect., Sept, 570 (1970)Google Scholar
3. Parker, J.W., Cox, M.E., Proc. SPIE, 713, 113 (1986)Google Scholar
4. Blyer, L.L., Lieberman, R.A., Cohen, L.G., Ferrera, J.A., MacChesney, J.B., Polym. Engr. and Sci., 29, 1215 (1989)Google Scholar
5. Wang, K., Seiler, K., Rusterholz, B. and Simon, W., Analyst, 117, 57–60 (1992)Google Scholar
6. Cox, M.E., Dunn, B., Appl. Opt., 24, 2114 (1985)Google Scholar
7. Gromov, D.A., Dyumaev, K.M., Manenkov, A.A., Maslyukov, A.P., Matyushin, G.A., Nechitailo, V.S., Prokhorov, A.M., J. Opt. Soc. Am. B, 2,1028 (1985)Google Scholar
8. Avnir, D., Kaufman, V.R. and Reisfeld, R., J. Noncryst. Solids, 74, 395–406 (1985)Google Scholar
9. Knobbe, E.T., Dunn, B., Fuqua, P.D., Nishida, F., Applied Optics, 29, 2729 (1990)Google Scholar
10. Dunn, B., Knobbe, E, McKiernan, J.M., Pouxviel, J.C., Zink, J.I., Better Ceramics Through Chemistry III, edited by Brinker, C. Jeffrey, Clark, David E., and Ulrich, Donald R. (Mater. Res. Soc. Proc. 121, Pittsburgh, PA, 1989), pp. 331–342.Google Scholar
11. Reisfeld, R., Brusilovsky, D., Eyal, M., SPIE v. 1182, French-Israeli Workshop on Solid State Lasers (1988)Google Scholar
12. Knobbe, E.T., Dunn, B. and Gold, M., Proceedings of SPIE, 906, 39–41 (1988)Google Scholar
13. Zusman, R.; Rottman, C.; Ottolenghi, M.; Avnir, D.; J. Noncryst Solids, 122, 107 (1990)Google Scholar
14. Porphyrins ani Metalloporphyrins, edited by Smith, K.M. (Elsevier Scientific, New York, 1975).Google Scholar
15. The Porphyrns, edited by Dolphin, D. (Academic Press, New York, 1978)Google Scholar
16. Pouxviel, J.C., Boilot, J.P., Dauger, A., Wright, A.C., J. Noncryst Solids, in pressGoogle Scholar