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Sodium Sulfur Battery Accomplishments and Remaining Problems

Published online by Cambridge University Press:  21 February 2011

Wilfried Fischer
Wilfried Fischer*
Affiliation:
Asea Brown Boveri, Eppelheimer Str. 82, D-6900 Heidelberg, Federal Republic of Germany
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Abstract

NaS batteries are at a state of development at which the principal problems are resolved and prototype batteries have been tested for major applications such as electric vehicle propulsion and off-peak electric energy storage in electric networks. An overview will be presented on the state of development and on application tests performed so far.

Nevertheless, cell and battery ccmponents need to be further optimized. Major areas for potential improvements are the beta alumina solid electrolyte with regard to conductivity, mechanical strength and life, the metal ceramic joint, the cell casing with regard to corrosion resistance, and the vacuum thermal enclosure with regard to a lower thermal conductivity. Possible solutions will be discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 541
Copyright
Copyright © Materials Research Society 1989

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References

/1/Fischer, W., Birnbreier, H. and Benninger, G.N., Proc. 21st IECBC, San Diego, Aug. 25 - 29 (1986) 1041 Google Scholar
/2/Angelis, J.W., Birnbreier, H. and Haase, H., Elektrische Bahnen, 85 (1987) 252 Google Scholar
/3/Hames, M.D. and Sudworth, J.L., Proc. of the Institution of Electrical Engineers 126 (1979) 1157 Google Scholar
/4/Molyneux, J., Sands, G. et al. , Proc. 22nd IECEC, Philadelphia, Pa., Aug. 10 - 14 (1987) 975 Google Scholar
/5/Auxer, W., Proc. 8th Battery and Electrochem. Contraotors Conf., Vienna, Va., Nov. 16 - 19 (1987) 59 Google Scholar
/6/Mulcahey, T.P., Tunimillo, A.F. et al. , 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987) 85 Google Scholar
/7/Gates, A.B., Proc. 18th IBEJC, Los Angeles, Ca., Aug. 21 -26 (1983) 1690 Google Scholar
/8/Minck, R.W., Proc. DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 4–13 Google Scholar
/9/Mori, S., Ogino, A. et al. , Abstr. No. 64, 170th Electrochem. Soc. Meeting, San Diego, Ca., Oct. 19 - 24 (1986) 94 Google Scholar
/10/Kita, A., Ncnura, E. et al. , 22nd IECEC, Philadelphia, Pa., Aug. 10 - 14 (1987) 1066 Google Scholar
/11/Fuchida, K., Okada, K. et al. , 17th IECEC, Los Angeles, Ca., Aug. 8 - 11 (1982) 591 Google Scholar
/12/Fischer, W. and Shiota, T., Electric Vehicle Symp. 9, Toronto, Nov. 13 - 16 (1988)Google Scholar
/13/Fischer, W., in “High Conductivity Solid Ionic Conductors”, Takahashi, T. edit., World Scientific Publishing Co., Singapore, in pressGoogle Scholar
/14/NcNamee, N., 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987) 41 Google Scholar
/15/Haskins, H.J. and Reitz, G.A., 8th Intern. Electric Vehicle Symp., Washington D.C., Oct. 20 - 22 (1986) 328 Google Scholar
/16/Hartmann, B. and Lehnert, G., Proc. DOE/EPRI Beta Battery Workshop VI, Snorbird, Utah, May 19 - 23 (1985) 6–147 Google Scholar
/17/Sudworth, J.L., Proc. DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 7–1Google Scholar
/18/Browall, K.W., Proc. DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 6–17 Google Scholar
/19/Gross, F. and Fischer, W., Progress in Batteries and Solar Cells 6 (1987) 30 Google Scholar
/20/Mc Clanahan, M.L., Proc. DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 6–25 Google Scholar
/21/Braithwaite, G.W., 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987)Google Scholar
/22/Reiss, H. and Ziegenbein, B., Proc. 8th Intern. Thermal Conductivity Conf., Rapid City, Oct. 3 - 5 (1983)Google Scholar
/23/Reiss, H., Spektrum der Wissenschaft, Nov. (1985) 112 Google Scholar
/24/Mangan, M.F., Ext. Abstr., 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987) 52 Google Scholar
/25/Chilenskas, A.A., Biwer, R.L. and Luca, W.H. De, Proc. 8th Intern. Electric Vehicle Syrmp., Washington D.C., Oct. 20 - 22 (1986) 338 Google Scholar
/26/Fischer, W., Birnbreier, H. and Benninger, G.N., Proc. 8th Intern. Electric Vehicle Symp., Washington D.C., Oct. 20 - 22 (1986) 324 Google Scholar
/27/Sudworth, J.L., EPRI-Report EM 3671-SR, Proc. DOE/EPRI Beta Battery Workshop V, Washington D.C., Oct. 18 - 20 (1983) 7–1Google Scholar
/28/Fischer, W., Seele, W., Devries, P. and Isozaki, T., DOE/EPRI Beta Battery Workshop VII, Toronto, May 31 - June 3 (1988)Google Scholar
/29/Yuasa/NGK Sparkplug-Report to NEDO, Aug. (1986)Google Scholar
/30/BBC-Druckschrift Nr. DHB 1221-87 D, 15.6. (1987)Google Scholar
/31/Electric Propulsion No. 3, 2 (1987) 6Google Scholar
/32/Angelis, J.W. and Sedgwick, D., DOE/EPRI Beta Battery Workshop VII, Toronto, May 31 - June 3 (1988)Google Scholar
/33/Electric Vehicle Progress 10, No. 3, Feb. 1 (1988)Google Scholar
/34/Harbach, F., Solid State Ionics 13 (1984) 53 Google Scholar
/35/Bates, J.B., Wang, G.C. and Dudney, J.C., Physics Today, July, (1982) 46 Google Scholar
/36/Dell, R.M. and Moseley, P.T., J. Power Sources 6 (1981) 143 Google Scholar
/37/Stevens, R. and Binner, J.G.P., J. Mat. Sci. 19 (1984) 695 CrossRefGoogle Scholar
/38/Virkar, A.V., Miller, G.R. and Gordon, R.S., J. Am. Ceram. Soc. 61 (1978) 250 Google Scholar
/39/Archer, W.L., Armstrong, R.D. et al. , J. Mat. Sci. 15 (1980) 2066 Google Scholar
/40/Kusakabe, Y. and Kawamoto, H., Electrochem. Soc. Meeting, Miami (1987)Google Scholar
/41/Youngblood, G.E., Miller, G.R. and Gordon, R.S., J. Am. Ceram. Soc. 61 (1978) 86 Google Scholar
/42/Armstrong, R.D., Dickinson, T. and Turner, J., Electrochim. Acta 19, (1974) 187 Google Scholar
/43/Virkar, A.V. and Viswanathan, L., J. Mat. Sci. 18 (1983) 1202 CrossRefGoogle Scholar
/44/Viswanathan, L. and Virkar, A.V., J. Mat. Sci. 17 (1982) 753 Google Scholar
/45/Virkar, A.V., Viswanathan, L. and Biswas, D.R., J. Mat. Sci. 15, (1980) 302 CrossRefGoogle Scholar
/46/Weiler, L., DOE/EPRI Beta Battery Workshop V, Washington D.C., Oct. 18 - 20 (1985)Google Scholar
/47/Ansell, R.O., J. Mat. Sci. 21 (1986) 365 CrossRefGoogle Scholar
/48/Buechele, A.C., Jonghe, L.C. De and Hitchcock, D., J. Electrochem. Soc. 130 (1983) 1042 CrossRefGoogle Scholar
/49/De Jonghe, L.C., EPRI-Report EM-3631-SR, DOE/EPRI Beta Battery Workshop V, Washington D.C., Oct. 18 - 20 (1983) 5–85 Google Scholar
/50/De Jonghe, L.C., Feldmann, L. and Buechele, A.C., J. Mat. Sci. 16 (1981) 780 Google Scholar
/51/De Jonghe, L.C., EPRI-Report EM-4151, July (1985)Google Scholar
/52/US-DOE Report ER-0168, June (1983)Google Scholar
/53/Steinleitner, G., DVS-Berichte 66 (1981) 784 Google Scholar
/54/Browall, K.W., DOE/EPRI Beta Battery Workshop V, Washington D.C., Oct. 18 - 20 (1983)Google Scholar
/55/Auxer, W., Proc. 8th Intern. Electric Vehicle Symip., Washington D.C., Oct. 20 - 22 (1986) 318 Google Scholar
/56/Freese, J.M., 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987) 79 Google Scholar
/57/Knödler, R., J. Appl. Electrochem. 18 (1987) 653 Google Scholar
/58/Smaga, J.H. and Battles, J.E., Ext. Abstr., 7th Battery and Electro-chem. Contractors Conf., Crystal City, Va., Nov. 18 - 21 (1985) 40 Google Scholar
/59/Park, D.S. and Chatterji, D., Thin Solid Films 83 (1981) 429 Google Scholar
/60/Iwabuchi, S., Progress in Batteries and Solar Cells 5 (1984) 310 Google Scholar
/61/Stackpool, F.M., DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 7–8 Google Scholar
/62/Bauer, R., Haar, W. et al. , J. Power Sources 1 (1976/1977) 109 Google Scholar
/63/Knbdler, R., DOE/EPRI Beta Battery Workshop VI, Snowbird, Utah, May 19 - 23 (1985) 7–15 Google Scholar
/64/Fischer, W., Dechema Monographien 92 (1982) 103 Google Scholar
/65/Wright, M.L. and Tilley, A.R., 16th IECDC, Atlanta, Ga., Aug. 9 - 14 (1981) 841 Google Scholar
/66/Battles, J.E. and Mrazek, F.C., EPRI-Report EM-4341, Research Project 1198-15, Dec. (1985)Google Scholar
/67/Reiss, H., AIPA 16th Thermophysics Conf., Palo Alto, Ca., June 23 - 25 (1981)Google Scholar
/68/Büttner, D., Kreh, A., Fricke, J. and Reiss, H., 11th Europ. Conf., Thermophys. Prop., Umea, Sweden, June (1988)Google Scholar
/69/Weaver, R.D., Smedley, S.I. and Kubre, M.C.H. Mc, 8th Battery and Electrochem. Contractors Conf., Vienna, Va., Nov. 16 - 19 (1987) 83 Google Scholar