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Small-Angle Neutron Scattering and 27Al Nmr Studies on the Microstructure and Composition of Alumina Sol-Gels

Published online by Cambridge University Press:  28 February 2011

L. F. Nazar ,
D. G. Napier ,
D. Lapham  and
E. Epperson
L. F. Nazar
Affiliation:
University of Waterloo, Department of Chemistry, Waterloo, Ontario, Canada
D. G. Napier
Affiliation:
University of Waterloo, Department of Chemistry, Waterloo, Ontario, Canada
D. Lapham
Affiliation:
University of Waterloo, Department of Chemistry, Waterloo, Ontario, Canada
E. Epperson
Affiliation:
Argonne National Laboratories, Materials Science Division
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Abstract

We have used small angle neutron scattering, static light scattering and 27Al NMR to examine the structure and composition of alumina sol-gels formed by the hydrolysis of aluminum alkoxides. For LT sols at low acid concentrations, and HT gels over a wide range of acid concentration, 27Al solution NMR suggests, by the dearth of spectral resonances, that high molecular weight species are being formed. Analysis of the small angle neutron scattering data in the Porod regime indicates these sol-gels exhibit a power-law dependence consistent with mass fractal dimensions ranging from 1.45 to 1.8. These fractal dimensions are consistent with models based on diffusion limited cluster aggregation. The fractal dimensions do not differ significantly between LT and HT sols at the same acid concentration. However, for both temperature regimes, the fractal dimension increases with increasing acid concentration, suggesting a progression to a more compact network. Static light scattering measurements indicate the Guiner radii of the cluster aggregates vary from 600 to 2000Å.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 180: Symposium A – Better Ceramics Through Chemistry IV , 1990 , 117
Copyright
Copyright © Materials Research Society 1990

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References

REFERENCES

1. Schaefer, D.W. and Keefer, K.D., Mat. Res. Soc. Symp. Proc., 73, 277 (1986);Google Scholar
1a Brinker, C.J., J. Non-Cryst. Solids, 100, 31 (1988).Google Scholar
2. Yoldas, B.E., J. Appl. Chem. Biotechnol., 23, 803 (1973).Google Scholar
3. Nazar, L.F. and Klein, L.C., J. Am. Ceram. Soc., 71, C85 (1988);Google Scholar
3a Nazar, L.F., Klein, L.C. and Napier, D.C., Mat. Res. Soc. Symp. Proc., 121, 133 (1988).Google Scholar
4. Nazar, L.F., Fu, G. and Bain, A.D., in preparation.Google Scholar
5. Nazar, L.F., Klein, L.C., Fu, G., Bain, A.D. and Napier, D.C., in preparation.Google Scholar
6. Schaefer, D.W., Science, 243, 1023 (1989); and references therein.Google Scholar
7. Jullien, R. and Botet, R., Aggregation and Fractal Aggregates, World Scientific Publishing, Singapore, 1987.Google Scholar
8. Rausch, W.V. and Bale, H.D., J. Chem. Phys., 40, 3391 (1964).Google Scholar
9. Schaefer, D.W., Shelleman, R.A., Keefer, K.D. and Martin, J.E., Physica, 140A, 105 (1986).Google Scholar
10. Axelos, M., Tchoubar, D., Bottero, J.Y. and Fiessinger, F., J. Physiqe, 46, 1587 (1985).Google Scholar