Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-09T15:16:13.868Z Has data issue: false hasContentIssue false
  • English
  • Français

Sintered Reaction-Bonded Silicon Nitride by Microwave Heating

Published online by Cambridge University Press:  25 February 2011

Terry N. Tiegs ,
James O. Kiggans JR.  and
Kristin L. Ploetz
Terry N. Tiegs
Affiliation:
Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6087
James O. Kiggans JR.
Affiliation:
Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6087
Kristin L. Ploetz
Affiliation:
Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6087
Get access

Abstract

Sintered silicon nitride has many desired properties, however, for most applications these materials are too expensive to compete with metal parts. Sintered reaction-bonded silicon nitride (SRBSN) is more economical, with raw material costs <27% those of comparable high-purity materials, making it competitive with metal parts. Conventional processing of SRBSN requires long nitridation times and a two-step firing process. Microwave (MW) heating reduces the reaction times and is performed in a one-step process, thereby simplifying the operation. The flexural strength of the MW-SRBSN is equivalent to the strength of some materials made from higher-cost powders. Thus, these materials may be appropriate for a number of applications.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 287: Symposium K – Silicon Nitride Ceramics–Scientific and Technological Advances , 1992 , 283
Copyright
Copyright © Materials Research Society 1993

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Katz, R. N., Nitrogen Ceramics 1976-1981, pp. 3–20 in Progress in Nitrogen Ceramics, ed. Riley, F. L., Martinus Nijhoff Pub., The Hague, Netherlands (1983).Google Scholar
2. Sheppard, L. M., “Cost-Effective Manufacturing of Advanced Ceramics,” Am. Ceram. Soc. Bull., 70[4]692–707(1991)Google Scholar
3. Quadir, T., Rice, R. W., Chakraverty, J. C., Breindel, J. A., and Wu, C. C., “Development of Lower Cost Si3 N4 ,” Ceram. Eng. Sci. Proc., 12[9-10]1952–1957(1991)Google Scholar
4. Schoenung, J. M., “Analysis of the Economics of Silicon Nitride Powder Production,” Am. Ceram. Soc. Bull., 70 [1] 112–116 (1991).Google Scholar
5. Das, S. and Curlee, T. R., “The Cost of Silicon Nitride Powder and the Economic Viability of Advanced Ceramics,” Am. Ceram. Soc. Bull., 71 [7] 1103–1111 (1992).Google Scholar
6. Schulz, R. B. and Johnson, D. R., “Transportation, Energy and Ceramics,” Ceram. Eng. Sci. Proc., 12[9-10]947–956(1991).Google Scholar
7. Moulson, A. J., “Reaction-Bonded Silicon Nitride: Its Formation and Properties,” J. Mater. Sci., Vol. 14, pp. 1017–1051 (1979)Google Scholar
8. Riley, F. L., “Nitridation and Reaction Bonding,” pp. 265–288 in Nitrogen Ceramics, Riley, F. L. (ed.), Noordhoff, Netherlands (1977)Google Scholar
9. Mangels, J. A. and Tennenhouse, G. J., “Densification of Reaction-Bonded Silicon Nitride,” Am. Ceram. Soc. Bull., 59 [12] 1216–1222 (1980).Google Scholar
10. Williams, R. M. and Ezis, A., “Slip Casting of Silicon Shapes and Their Nitriding,” Am. Ceram. Soc. Bull., 62 [5] 607–619 (1983).Google Scholar
11. Ezis, A., “The Fabrication and Properties of Slip-Cast Silicon Nitride,” in Ceramics for High Performance Applications, Brook Hill Publishing Co., 207–222 (1974).Google Scholar
12. Tiegs, T. N., Kiggans, J. O., and Kimrey, H. D., “Microwave Processing of Silicon Nitride,” pp. 267–272 in Microwave Processing of Materials-II, Vol. 189, Materials Research Soc., Pittsburgh, PA 1991.Google Scholar
13. Kiggans, J. O., Hubbard, C. R., Steele, R. R., Kimrey, H. D., Holcombe, C. E., and Tiegs, T. N., “Characterization of Silicon Nitride Synthesized By Microwave Heating,” in Ceramic Transactions, Microwaves, Theory, and Applications in Materials Processing, Am. Cer. Soc., Westerville, Ohio, 267–272 (1991).Google Scholar
14. Kiggans, J. O. and Tiegs, T. N., “Characterization of Sintered Reaction Bonded Silicon Nitride Processed By Microwave Heating,” pp. 285–290 in Microwave Processing of Materials-HI, Vol. 269, Materials Research Soc., Pittsburgh, PA 1992.Google Scholar
15. Tiegs, T. N., Kiggans, J. O., and Ploetz, K. L., “Cost-Effective Sintered Reaction-Bonded Silicon Nitride for Structural Ceramics” to be published in Ceramic Engineering and Science Proceedings, American Ceramic SocietyGoogle Scholar
16. Binner, J. G. P., “Microwave Processing of Ceramics,” Brit. Ceram. Proc., 45, 97–108 (1990).Google Scholar
17. Tiegs, T. N. and Kiggans, J. O., “Fabrication of Silicon Nitride Ceramics by Microwave Heating,” pp. 665–671 in Proc. 4th International Symp. Ceram. Mater. & Compon. for Engines, Elsevier Applied Sci., New York (1992).Google Scholar
18. Tiegs, T. N. and Kiggans, J. O., and Kimrey, H. D., “Microwave Sintering of Silicon Nitride,” Ceram. Eng. Sci. Proc., 12[9-10] 1981–1992 (1991).Google Scholar
19. Mangels, J. A., “Sintered Reaction-Bonded Silicon Nitride,” Ceram. Eng. Sci. Proc., 2[7-8] 589–603 (1981).Google Scholar
20. Stephen, R. G. and Riley, F. L., “The Influence of Pre-Oxidation on the Processing of Silicon Powder,” pp. 307–314 in 4th Internat. Symp. on Ceram. Mater. Components for Engines, Elsevier Applied Science, NY (1992)Google Scholar