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Single-Photon Ionization, In Situ Optical Diagnostic Of Molecular Beam Epitaxial Growth Of GaAs

Published online by Cambridge University Press:  15 February 2011

Adina K. Ott ,
Sean M. Casey ,
April L. Alstrin  and
Stephen R. Leone
Adina K. Ott
Affiliation:
JILA, National Institute of Standards and Technology and University of Colorado, and Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309–0440
Sean M. Casey
Affiliation:
National Research Council Postdoctoral Fellow, National Institute of Standards and Technology
April L. Alstrin
Affiliation:
Present address, Quantum, 2270 S. 88th St., Louisville, CO 80028
Stephen R. Leone
Affiliation:
Staff member, Quantum Physics Division, National Institute of Standards and Technology
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Abstract

Single-photon ionization time-of-flight mass spectrometry (SPI-TOFMS) is used in situ to monitor desorbing species and surface reactions during molecular beam epitaxy (MBE) of GaAs. In this method, the 1064 nm fundamental output of a Nd:YAG laser is tripled twice to produce 118 nm (10.5 eV) photons. The pulsed light is passed in front of a growing substrate, giving gaseous scattered molecules sufficient energy to ionize, but not fragment, them. Ionized species are detected with time-of-flight mass spectrometry. Arrangement of the experiment also allows for simultaneous real time monitoring with reflection high-energy electron diffraction (RHEED).

Mass spectra are examined and analyzed to quantify fluxes and relative ionization cross sections of growth species. The real time behavior of arsenic and gallium mass signals during epitaxy is presented as a function of substrate temperature and incident gallium flux. Surface reactions are proposed to elucidate mechanisms of arsenic incorporation and compared to measured RHEED results.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 406: Symposium L – Diagnostic Techniques for Semiconductor Materials Processing , 1995 , 101
Copyright
Copyright © Materials Research Society 1996

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References

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